Free Benzene and Aromatic Compounds MCQs with Answers

172 Benzene and Aromatic Compounds MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Benzene has a planar ring of delocalised π electrons, giving aromatic stability and equal carbon-carbon bond lengths. The topic covers resonance, electrophilic substitution reactions such as nitration, halogenation, sulphonation and Friedel-Crafts reactions, along with substituent effects and the distinction between substitution in benzene and addition in ordinary alkenes.

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172 questions · page 8 of 9

  • A. Acetyl chloride
  • B. Acetic acid
  • C. Ethyl benzene
  • D. Ethanoic acid

Explanation: The benzene reacts with acetyl chloride in presence of anhydrous aluminum chloride to form acetophenone.

Correct answer: Acetyl chloride
  • A. Nitration
  • B. Ammonolysis
  • C. Sulphonation
  • D. Reduction of benzene

Explanation: Nitration reactions are the addition of a nitro group into an organic compound.

Correct answer: Nitration
  • A. Acylation
  • B. Carbonyl reduction
  • C. Alkylation
  • D. Formylation

Explanation: The introduction of an RC(O)+ group (also called an acyl group) in benzene is called acylation.

Correct answer: Acylation
  • A. Option A
  • B. Option B
  • C. Option C
  • D. Option D

Explanation: We are asked to describe the possible product of bromination. From the question, we can possibly conclude that the OH group is already…

Correct answer: Option C
  • A. Option A
  • B. Option B
  • C. Option C
  • D. Option D

Explanation: This set of reaction is known as Friedal Craft Acylation and in this, CH3CH3COCl i.e propanoyl chloride reacts with benzene and the…

Correct answer: Option D
  • A. ii, iii, iv
  • B. ii, iii
  • C. i, iv
  • D. i, ii, iv

Explanation: The 3 5 directing groups or Meta directing groups are as follows:Aldehyde (-CHO), Ketone (-CO-), Ester (-RCOOR'), Carboxyl Group (-COOH)…

Correct answer: ii, iii
  • A. CH3CO+
  • B. AlCl3
  • C. CH3+
  • D. CH3COCl

Explanation: CH3COCl reacts with AlCl3 to form ----> AlCl4- and CH3CO+CH3CO+ has a positive charge thus it is an electrophile and attracted to…

Correct answer: CH3CO+
  • A. Electrophilic addition
  • B. Electrophilic substitution
  • C. Nucleophilic substitution
  • D. Nucleophilic addition

Explanation: Benzene has an extended delocalised pi system above and below the ring which makes it highly attracted to electron-deficient species…

Correct answer: Electrophilic substitution
  • A. Br+
  • B. FeCl4+
  • C. Fe2+
  • D. Fe3+

Explanation: Benzene reacts with bromine in an electrophilic substitution reaction, but only in the presence of a catalyst to yield bromobenzene.

Correct answer: Br+
  • A. Benzoic acid
  • B. Methyl benzene
  • C. Benzaldehyde
  • D. Nitrobenzene

Explanation: Activating groups increase the reactivity of electrophilic substitutions, whereas deactivating groups decrease it.Activating groups are…

Correct answer: Methyl benzene
  • A. m-directing
  • B. o-directing
  • C. o -& p -directing & deactivating
  • D. o -& p -directing & activating

Explanation: Chlorine has a lone pair, so it can donate electrons to the benzene ring.

Correct answer: o -& p -directing & deactivating
  • A. C2H5
  • B. SO3H
  • C. NH2
  • D. CH3

Explanation: order of activating group (NH2, NHR, NHCOCH3, OCH3,CH3,C2H5(and deactivating group (NO2, CN, CHO, COR, COOH, COOR, SO3H)to increase and…

Correct answer: SO3H
  • A. A cyclic compounds
  • B. Ali cyclic compounds
  • C. Hetro cyclic compounds
  • D. Aromatic compounds

Explanation: Aromatic compounds are a class of cyclic organic compounds that contain one or more rings with a special stability due to the…

Correct answer: Aromatic compounds
  • A. R
  • B. OH
  • C. COR
  • D. NH2

Explanation: The acyl group (COR) is not ortho para directing and activating. It is a deactivating group due to the presence of the carbonyl group…

Correct answer: COR
  • A. -OH
  • B. -OR
  • C. -NH2
  • D. -CN

Explanation: -CN (Cyano group) is a deactivating group. It withdraws electron density from the ring through the inductive effect, reducing the…

Correct answer: -CN
  • A. of its cyclic nature
  • B. of having three double bonds
  • C. of aromatic character
  • D. of delocalization of electrons

Explanation: The correct answer is that benzene undergoes substitution reactions more easily due to the delocalization of electrons.

Correct answer: of delocalization of electrons
  • A. An aromatic compound cannot be completely converted into CO2 and other products during burning
  • B. The available amount of oxygen present in the air is not sufficient to completely burn the available compound
  • C. Aromatic compounds produce compounds on burning that are of black color
  • D. None of the above

Explanation: Aromatic compounds produce a smoky flame when burned due to their high carbon content.

Correct answer: The available amount of oxygen present in the air is not sufficient to completely burn the available compound
  • A. slower rate
  • B. faster rate
  • C. same rate
  • D. depends on the conditions

Explanation: Compared to benzene, nitration of toluene occurs at a faster rate due to the presence of the methyl group (-CH3), which is an…

Correct answer: faster rate
  • A. PVC
  • B. Benzene
  • C. Toluene
  • D. Teflon

Explanation: Benzene is formed by the cyclic trimerization of three ethyne (acetylene) molecules in a chemical process that rearranges the atoms into a…

Correct answer: Benzene
  • A. They have ring structure of carbon atoms.
  • B. They have a relatively high percentage of hydrogen atoms.
  • C. They have a relatively high percentage of carbon atoms.
  • D. They resist reactions with air/oxygen.

Explanation: The aromatic compound displays aromaticity. They burn with a strong sooty yellow flame.

Correct answer: They have a relatively high percentage of carbon atoms.