Free Benzene and Aromatic Compounds MCQs with Answers

172 Benzene and Aromatic Compounds MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Benzene has a planar ring of delocalised π electrons, giving aromatic stability and equal carbon-carbon bond lengths. The topic covers resonance, electrophilic substitution reactions such as nitration, halogenation, sulphonation and Friedel-Crafts reactions, along with substituent effects and the distinction between substitution in benzene and addition in ordinary alkenes.

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172 questions · page 7 of 9

  • A. Between the C-C bonds of benzene
  • B. Above and below the carbon bonds
  • C. In the form of cloud above and below the benzene ring
  • D. None of these

Explanation: Benzene is a cyclic molecule in which all of the ring atoms are sp2-hybridized.

Correct answer: In the form of cloud above and below the benzene ring
  • A. Between the C-C bonds of benzene
  • B. Above and below the carbon bonds
  • C. In the form of a cloud above and below the benzene ring
  • D. None of these options is correct

Explanation: All of the carbon atoms in the benzene rings are sp2-hybridized: the overlap of the sp2 orbitals around the ring produces a framework of…

Correct answer: In the form of a cloud above and below the benzene ring
  • A. Increase electron density at the ortho and para positions
  • B. Decrease electron density at the ortho and para positions
  • C. Make benzene less reactive
  • D. Both Options B and C are correct

Explanation: The meta groups deactivate the ring, by the inductive effect, in the presence of an electronegative atom, that withdraws the electrons…

Correct answer: Both Options B and C are correct
  • A. Anthracene
  • B. Naphthalene
  • C. Phenol
  • D. None of these options is correct

Explanation: All of these compounds contain a benzene ring, hence all are aromatic.

Correct answer: None of these options is correct
  • A. In alkynes to identify the position of the triple bond
  • B. In arenes to identify the position of the first substitution
  • C. In arenes to identify the position of the second substitution
  • D. In all hydrocarbons to identify the position of the functional group

Explanation: The terms ortho, meta, and para are prefixes used in organic chemistry to indicate the position of non-hydrogen substituents on a…

Correct answer: In arenes to identify the position of the second substitution
  • A. Three triple bonds
  • B. Two double bonds
  • C. Three double bonds
  • D. No multiband

Explanation: Option C is correct since benzene is a hydrocarbon composed of six carbons connected via a covalent bond, and exists in the form of a…

Correct answer: Three double bonds
  • A. The two isomers of benzene
  • B. The isomers of arenes
  • C. The two-resonance structure of benzene
  • D. The two-resonance structure of phenols

Explanation: This option is correct because kekule structure represents the resonating structure of benzene according to which benzene has a ring…

Correct answer: The two-resonance structure of benzene
  • A. Two double bonds
  • B. Delocalized pi-electron charge
  • C. Three double bonds
  • D. One sigma bond

Explanation: Benzene has a delocalized pi-electron system. Its alternative double bonds cause the ring to become delocalized and constitute the…

Correct answer: Delocalized pi-electron charge
  • A. Two Double Bonds
  • B. Delocalized Pi-Electron Charge
  • C. Three Double Bonds
  • D. One Sigma Bond

Explanation: Benzene is a cyclic molecule in which all of the ring atoms are sp2-hybridized and contain double bonds.

Correct answer: Delocalized Pi-Electron Charge
  • A. Benzene
  • B. Toluene
  • C. Phenol
  • D. Diphenylmethane

Explanation: Diphenylmethane is a synthetic compound manufactured by 'The Friedel-Craft Reaction' of benzyl chloride with benzene in the presence of…

Correct answer: Diphenylmethane
  • A. Ortho
  • B. Meta
  • C. Para
  • D. None of these

Explanation: Disubstituted benzene rings can be named based on the relative positions of the substituents: the prefix para is used iif they are found…

Correct answer: Para
  • A. 154 pm
  • B. 120 pm
  • C. 134 pm
  • D. 139 pm

Explanation: The C−C bond length in benzene is 139 pm. All C−C and C=C bond lengths are the same in benzene.

Correct answer: 139 pm
  • A. Alicyclic
  • B. Aliphatic compounds
  • C. Aromatic compounds
  • D. Acyclic compounds

Explanation: Correct option is C. Aromatic compounds, also known as "mono- and polycyclic aromatic hydrocarbons", are organic compounds containing one…

Correct answer: Aromatic compounds
  • A. Three triple bonds
  • B. Two double bonds
  • C. Three double bonds
  • D. No multiband

Explanation: Correct option is C. There are 3 double bonds in benzene. Six single bonds between Carbons and Hydrogens, three single bonds between six…

Correct answer: Three double bonds
  • A. -COOH
  • B. -COR
  • C. -CN
  • D. -OH

Explanation: "-OH" group favors electrophilic attack ortho or para to the substituent while the other group of options doesn't hence the answer is D.

Correct answer: -OH
  • A. Aldol condensation
  • B. Wolf kishner reaction
  • C. Wittig reaction
  • D. Friedel and craft reaction

Explanation: The reaction in which benzene is reacted with alkyl or acyl halide in the presence of AlCl3 is called Friedel-Craft reaction.

Correct answer: Friedel and craft reaction
  • A. It has low melting and low boiling points
  • B. It has high melting and high boiling points
  • C. It has low melting and high boiling points
  • D. It has a high solubility in polar solvents

Explanation: Arenes are aromatic compounds (contain benzene rings). Hence, they only possess weak Vander Waal's forces as their intermolecular forces…

Correct answer: It has low melting and low boiling points
  • A. NO2-
  • B. HNO2
  • C. NO3-
  • D. NO2+

Explanation: Explanation:During the nitration of benzene which is an electrophilic substitution reaction, the active nitrating agent is NO2+.

Correct answer: NO2+
  • A. Alkyl group
  • B. Phenyl group
  • C. Benzyl group
  • D. Methyl group

Explanation: A is incorrect as alkyl group is formed when one hydrogen is removed from an alkane chain;not a benzene ring.B is correct as when one…

Correct answer: Phenyl group
  • A. Conc. HNO3 and conc. HCl
  • B. Conc. HNO3 and conc. Acetic acid
  • C. Conc. HNO3 and H3PO4
  • D. Conc. HNO3 and conc. H2SO4

Explanation: A is incorrect as these reactants are not used in nitration.B is incorrect as these reactants are not used in nitration.C is incorrect as…

Correct answer: Conc. HNO3 and conc. H2SO4