Free Benzene and Aromatic Compounds MCQs with Answers

172 Benzene and Aromatic Compounds MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Benzene has a planar ring of delocalised π electrons, giving aromatic stability and equal carbon-carbon bond lengths. The topic covers resonance, electrophilic substitution reactions such as nitration, halogenation, sulphonation and Friedel-Crafts reactions, along with substituent effects and the distinction between substitution in benzene and addition in ordinary alkenes.

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172 questions · page 6 of 9

  • A. Alkylation
  • B. Halogenation
  • C. Nitration
  • D. Acylation

Explanation: Acetophenone is formed by friedal craft acylation. This reaction involves acylation of benzene with acyl chloride or acyl anhydride

Correct answer: Acylation
  • A. HSO4-
  • B. H2SO4
  • C. SO3
  • D. HSO3

Explanation: SO3 acts as an electrophile in sulphonation. Sometimes H2SO4 is also seen in equations in place of SO3 because H2SO4 dissociates to give…

Correct answer: SO3
  • A. Good electrophile
  • B. Good nucleophile
  • C. Resonance hybrid
  • D. Extraordinary stable

Explanation: Benzene is a nucleophile because of its delocalized electrons thus the molecule has electron-rich areas which are frequently attacked by…

Correct answer: Good nucleophile
  • A. In alkynes to identify the position of triple bond
  • B. In arenes to identify the position first substitution
  • C. In arenes to identify the position second substituition
  • D. In all hydrocarbons to identify the position of functional group

Explanation: Ortho, para, and meta are prefixes used to designate the relative positions of second substituent groups on an aromatic ring in organic…

Correct answer: In arenes to identify the position second substituition
  • A. Numerically
  • B. Alphabetically
  • C. Alphanumerically
  • D. None of these options is correct

Explanation: The substituents in arenes are put in alphabetical order when they are different.

Correct answer: Alphabetically
  • A. Low melting and low boiling points
  • B. High melting and high boiling points
  • C. Low melting and high boiling points
  • D. High solubility in polar solvents

Explanation: OPTION A: Arenes are compounds that contain benzene ring(s). Since the only possible intermolecular force of attraction, in this case, are…

Correct answer: Low melting and low boiling points
  • A. Elimination
  • B. Addition
  • C. Substitution
  • D. Hydrogenation

Explanation: Option A: There is no such evidence of elimination reaction in Benzene since it completely destroys the stability of Benzene.Addition…

Correct answer: Elimination
  • A. Hydrogenation
  • B. Dehydrogenation
  • C. Dehydration
  • D. None of these options are correct

Explanation: Dehydrogenation is the process by which hydrogen is removed from an organic compound to form a new chemical (e.g., to convert saturated…

Correct answer: Dehydrogenation
  • A. Benzene reactivity
  • B. That benzene has dual character
  • C. That benzene has less heat of formation
  • D. All of these options are correct

Explanation: Kekule's structure does not explain the extra ordinary stable nature of benzene molecule and its lack of reactivity towards addition…

Correct answer: All of these options are correct
  • A. Tetrahedral
  • B. Hexagonal planar
  • C. Hexagonal irregular
  • D. Trigonal planar

Explanation: A benzene ring has 6 carbons hence it is a hexagon and it is hexagonal planar and not hexagonal irregular because all the carbons are in…

Correct answer: Hexagonal planar
  • A. FeBr3
  • B. FeCl4-
  • C. Cl+
  • D. Cl-

Explanation: Electrophiles are species with a positive charge. The only element/molecule with a positive charge is Cl hence, Option C is the correct…

Correct answer: Cl+
  • A. Hexagonal planar
  • B. Square planar
  • C. Trigonal planar
  • D. Linear

Explanation: Benzene has 6 carbons, hence it is given the name hexagon. All the carbons are in the same planar hence it is called planar.

Correct answer: Hexagonal planar
  • A. KMnO4
  • B. K2Cr2O7
  • C. KHMnO4
  • D. V2O5

Explanation: Vanadium pentoxide (V2O5) can be used as an oxidizing agent to oxidize benzene and its derivatives under specific conditions.

Correct answer: V2O5
  • A. Two
  • B. One
  • C. Three
  • D. None of these

Explanation: Benzene can form only one type of monosubstituted means that it cannot form different atoms just by replacing the position of the attached…

Correct answer: One
  • A. Pyrrole
  • B. Furan
  • C. Thiophene
  • D. All

Explanation: In benzene derivatives, all the atoms that make up the ring are carbon atoms.

Correct answer: All
  • A. Increases electron density
  • B. Decrease electron density on benzene
  • C. Make benzene less reactive
  • D. None of these

Explanation: The electron donating group such as the alkyl group donates electrons to the benzene ring and hence increases the density.

Correct answer: Increases electron density
  • A. Elimination
  • B. Addition
  • C. Substitution
  • D. Dehydration

Explanation: There is no such evidence of an elimination reaction in Benzene since it completely destroys its stability.Benzene generally also resists…

Correct answer: Elimination
  • A. Ortho-xylene
  • B. Para-xylene
  • C. Para-methyl toluene
  • D. Meta-methyl toluene

Explanation: Xylene is any of three organic compounds with the formula (CH3)2C6H4. They are derived from the substitution of two hydrogen atoms with…

Correct answer: Para-xylene
  • A. Alkyl group
  • B. Benzyl group
  • C. Phenyl group
  • D. Ethyl group

Explanation: Reason: A benzene ring has the formula of C6H6. When a hydrogen atom is removed, this becomes C6H5. C6H5 is known as a phenyl group.

Correct answer: Phenyl group
  • A. Highly saturated
  • B. Highly unsaturated
  • C. Gives substitution reactions
  • D. Gives elimination reactions

Explanation: Option B. Kekule formula with three double bonds demands a high degree of unsaturation from benzene while usually it exhibits a saturated…

Correct answer: Highly unsaturated