Asked in PMC National MDCAT 2020 2020Moderate

Electrophile in sulphonation of benzene is:

Correct answer: C. SO3

  • A. HSO4-
  • B. H2SO4
  • C. SO3
  • D. HSO3

Explanation

SO3 acts as an electrophile in sulphonation. Sometimes H2SO4 is also seen in equations in place of SO3 because H2SO4 dissociates to give SO3, which in turn acts as an electrophile that's why B is not the best choice.

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About Benzene and Aromatic Compounds

Benzene has a planar ring of delocalised π electrons, giving aromatic stability and equal carbon-carbon bond lengths. The topic covers resonance, electrophilic substitution reactions such as nitration, halogenation, sulphonation and Friedel-Crafts reactions, along with substituent effects and the distinction between substitution in benzene and addition in ordinary alkenes.

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