Free s-Block and p-Block Elements MCQs with Answers

1,359 s-Block and p-Block Elements MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

The s and p blocks are studied through their valence-shell configurations, periodic trends and characteristic chemical properties. Work covers the reactions of Group I and Group II elements, the behaviour of Group IV elements, and how atomic size, ionization energy, electronegativity and metallic character change across periods and down groups.

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Read the s-Block and p-Block Elements notesFree MDCAT chapter notes with key terms

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Moderate
  • A. decreases, because nuclear charge increases while electrons enter the same shell
  • B. increases, because more electrons are added
  • C. stays the same
  • D. increases, because the nuclear charge decreases

Explanation: Each successive element adds one proton and one electron, but the electron enters the same outermost shell, so shielding hardly changes…

Correct answer: decreases, because nuclear charge increases while electrons enter the same shell
Very hard
  • A. add one electron to a gaseous atom
  • B. remove one mole of electrons from one mole of gaseous atoms, forming gaseous unipositive ions
  • C. break one mole of covalent bonds
  • D. convert one mole of a solid into a gas

Explanation: The definition specifies the gaseous state so that no lattice or intermolecular forces interfere, and it is always endothermic because an…

Correct answer: remove one mole of electrons from one mole of gaseous atoms, forming gaseous unipositive ions
  • A. Oxygen
  • B. Chlorine
  • C. Fluorine
  • D. Nitrogen

Explanation: Fluorine is the most electronegative element on the Pauling scale at 4.0, because it is small and has a high effective nuclear charge, so…

Correct answer: Fluorine
Hard
  • A. decreases, because atomic radius increases
  • B. stays constant
  • C. decreases, because ionisation energy falls
  • D. increases, because the outer electron is further from the nucleus and more easily lost

Explanation: Each element down the group has an extra shell, so the single outer electron is further from the nucleus and better shielded, ionisation…

Correct answer: increases, because the outer electron is further from the nucleus and more easily lost
  • A. are found free in nature
  • B. react with water to form hydroxides that are strongly basic
  • C. are all radioactive
  • D. form acidic oxides

Explanation: Sodium and its neighbours react with water to give hydrogen and a hydroxide solution that is strongly alkaline, which is the origin of the…

Correct answer: react with water to form hydroxides that are strongly basic
  • A. sodium oxide, Na2O
  • B. sodium superoxide, NaO2
  • C. sodium peroxide, Na2O2
  • D. sodium hydroxide, NaOH

Explanation: Lithium forms the simple oxide, sodium forms mainly the peroxide and potassium, rubidium and caesium form superoxides, the larger cations…

Correct answer: sodium peroxide, Na2O2
Hard
  • A. less reactive, with higher melting points and harder solids
  • B. more reactive in every case
  • C. non metallic in character
  • D. monovalent in their compounds

Explanation: Group II atoms are smaller and must lose two electrons rather than one, so more energy is needed and they are less reactive than their…

Correct answer: less reactive, with higher melting points and harder solids
  • A. decreases down the group
  • B. is the same for all
  • C. increases down the group
  • D. first increases then decreases

Explanation: A small, highly charged cation polarises the carbonate ion strongly and weakens the carbon to oxygen bonds, so magnesium carbonate…

Correct answer: increases down the group
  • A. Barium sulphate
  • B. Magnesium hydroxide
  • C. Calcium carbide
  • D. Beryllium chloride

Explanation: Magnesium hydroxide, sold as milk of magnesia, is a weak insoluble base that neutralises excess stomach acid without being absorbed in…

Correct answer: Magnesium hydroxide
  • A. metallic carbon to non metallic lead
  • B. non metallic carbon through metalloid silicon and germanium to metallic tin and lead
  • C. entirely metallic throughout
  • D. entirely non metallic throughout

Explanation: Carbon is a non metal, silicon and germanium are metalloids used as semiconductors, and tin and lead are true metals, so group IV shows…

Correct answer: non metallic carbon through metalloid silicon and germanium to metallic tin and lead
  • A. decreases down the group
  • B. is the same throughout
  • C. is zero for all members
  • D. increases down the group, so lead two compounds are more stable than lead four

Explanation: This is the inert pair effect: the two s electrons of the outer shell become progressively harder to involve in bonding as the group is…

Correct answer: increases down the group, so lead two compounds are more stable than lead four
Very hard
  • A. the number of shells it has
  • B. its atomic mass
  • C. the subshell that receives the last electron added
  • D. whether it is a metal or a non metal

Explanation: Elements are assigned to the s, p, d or f block according to the subshell into which the differentiating electron enters, so groups I and…

Correct answer: the subshell that receives the last electron added
  • A. group VI of the p block, period 3
  • B. group IV of the p block, period 3
  • C. group II of the s block, period 3
  • D. group VI of the d block, period 4

Explanation: The outermost shell is the third, giving period 3, and it contains six electrons in total across 3s and 3p, giving group VI, while the…

Correct answer: group VI of the p block, period 3
  • A. decreases, because atomic size increases
  • B. increases, because the atoms get smaller and the nuclear charge increases
  • C. remains constant
  • D. decreases, because shielding increases sharply

Explanation: A greater nuclear charge acting on a shell at nearly constant distance holds the outer electrons more tightly, so more energy is needed to…

Correct answer: increases, because the atoms get smaller and the nuclear charge increases
  • A. acidic through amphoteric to basic
  • B. acidic to neutral only
  • C. basic through amphoteric to acidic
  • D. neutral to basic

Explanation: Sodium and magnesium oxides are basic, aluminium oxide is amphoteric and reacts with both acids and alkalis, and the oxides of phosphorus…

Correct answer: basic through amphoteric to acidic
  • A. sodium
  • B. magnesium
  • C. beryllium
  • D. aluminium

Explanation: Lithium resembles magnesium because their ions have similar size to charge ratios, so both form nitrides directly with nitrogen, both give…

Correct answer: magnesium
Moderate
  • A. calcium oxide and hydrogen
  • B. calcium hydride and oxygen
  • C. calcium hydroxide and hydrogen
  • D. calcium carbonate and hydrogen

Explanation: Calcium reacts steadily with cold water to give a suspension of slightly soluble calcium hydroxide, known as limewater when filtered…

Correct answer: calcium hydroxide and hydrogen
Hard
  • A. golden yellow
  • B. brick red
  • C. apple green
  • D. lilac

Explanation: Heating excites the outer electron to a higher level and the colour is emitted as it falls back, the energy gap being characteristic of…

Correct answer: lilac
  • A. First ionisation energy
  • B. Electronegativity
  • C. Solubility of the hydroxides in water
  • D. Melting point of the metal

Explanation: Hydroxide solubility rises down the group, so magnesium hydroxide is only sparingly soluble while barium hydroxide dissolves appreciably…

Correct answer: Solubility of the hydroxides in water
  • A. is small, has no available d orbitals and forms strong multiple bonds with itself
  • B. has a much larger atomic radius
  • C. is a metal
  • D. has a full outer shell

Explanation: Its small size lets carbon form stable double and triple bonds and catenate into long chains, which is the basis of the whole of organic…

Correct answer: is small, has no available d orbitals and forms strong multiple bonds with itself

s-Block and p-Block Elements MCQs: common questions

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