Free Fundamental Principles of Organic Chemistry MCQs with Answers

536 Fundamental Principles of Organic Chemistry MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Organic chemistry begins with carbon compounds classified by carbon skeleton, saturation and functional group. Work includes identifying groups such as hydroxyl, carbonyl, carboxyl and amino, applying basic nomenclature, and distinguishing structural, geometric and optical isomers, where the same molecular formula does not necessarily mean the same structure or properties.

Last updated

Read the Fundamental Principles of Organic Chemistry notesFree MDCAT chapter notes with key terms

536 questions · page 15 of 27

  • A. Steam cracking
  • B. Reforming
  • C. Catalytic cracking
  • D. Distillation

Explanation: Reforming is used to improve the quality of gasoline because it converts low-octane naphtha into high-octane reformates.

Correct answer: Reforming
  • A. Carbon
  • B. Hydrogen
  • C. Potassium
  • D. Hydrocarbons

Explanation: Hydrocarbons are organic compounds that contain only hydrogen and carbon.

Correct answer: Hydrocarbons
  • A. CH3 -O- CH2 - CH3
  • B. CH3 - CO - CH2 - CH3
  • C. CH3COCOOH
  • D. CH3 - CH2CHO

Explanation: The correct answer is Option B: CH3 - CO - CH2 - CH3. This compound is a ketone with the general formula R-CO-R', and its chemical name is…

Correct answer: CH3 - CO - CH2 - CH3
  • A. Catalytic cracking
  • B. Steam cracking
  • C. Thermal cracking
  • D. All of these

Explanation: Catalytic cracking produces gasoline of higher octane number and, therefore, this method is used for obtaining better quality gasoline.

Correct answer: Catalytic cracking
  • A. Alicyclic
  • B. Aliphatic compounds
  • C. Aromatic compounds
  • D. Acyclic compounds

Explanation: The compounds in which the ring consists of only carbon atoms are Homocyclic or carbocyclic compounds.

Correct answer: Aromatic compounds
  • A. Thermal cracking
  • B. Catalytic cracking
  • C. Steam cracking
  • D. Reforming

Explanation: Catalytic cracking is a process in which complex hydrocarbons are broken down into simpler molecules.

Correct answer: Catalytic cracking
  • A. CHCl = CCl2 and CH2 = CH2
  • B. CHCI= CH2 and CH2 = CHCl
  • C. CH3 - CH=CH - CH3 and H3C-CH = CH - CH3
  • D. CH3 - CH3 and CH2 - CH2

Explanation: Cis-trans isomerism specifically refers to the arrangement of groups around a double bond.

Correct answer: CH3 - CH=CH - CH3 and H3C-CH = CH - CH3
  • A. Cyano compounds
  • B. Nitro compounds
  • C. Carbon nitrogen molecule
  • D. Imines

Explanation: Compounds having the C = NH group are called imines. An imine is a functional group or chemical compound that contains a carbon-nitrogen…

Correct answer: Imines
  • A. 1-Bromo-2-chloropropene
  • B. 2-Pentene
  • C. 2.3-Dimethylpropene
  • D. Both A and B

Explanation: Option D is correct because both options A and B are correct. 1-Bromo-2-chloropropene (CH3 CCl=CH2Br) exhibits geometric isomerism due to…

Correct answer: Both A and B
  • A. Aromatic compounds
  • B. Alicyclic compounds
  • C. Aliphatic compound
  • D. Heterocyclic compounds

Explanation: The cyclobutane structure is categorized under alicyclic compounds. Alicyclic compounds are a type of organic compounds that contain one…

Correct answer: Alicyclic compounds
  • A. 500°C, 2atm
  • B. 900°C. 2atm
  • C. 500°C. 4atm
  • D. 900°C. 4atm

Explanation: The temperature for catalytic cracking is usually in the range of 450°C to 550°C.

Correct answer: 500°C, 2atm
  • A. -COOH
  • B. -COOR
  • C. -CO-O-CO
  • D. -CO-

Explanation: Option D is correct because an anhydride is a functional group that consists of two acyl groups (R-CO-) linked by an oxygen atom.

Correct answer: -CO-O-CO
  • A. Hydroxyl group
  • B. Benzene group
  • C. Aldehyde group
  • D. Carboxylic acid group

Explanation: Benzene is just a homounsaturatedcyclic compound which follows Huckle's Rule and classified as an aromatic comound.

Correct answer: Benzene group
  • A. Cyclohexane
  • B. Cyclohexene
  • C. Tetrahydrofuran
  • D. Acetic acid

Explanation: Acetic acid is the correct answer as it is not an alicyclic compound. Unlike alicyclic compounds that have a cyclic structure, acetic acid…

Correct answer: Acetic acid
  • A. Sigma bonds
  • B. Pi bonds
  • C. Hydrogen bonds
  • D. None of these

Explanation: Pi bonds are formed by the overlap of two parallel p orbitals. Pi bonds are present in alkenes and alkynes, but not in alkanes.

Correct answer: Pi bonds
  • A. Methanol
  • B. Diethyl ether
  • C. Acetone
  • D. Dimethyl ether

Explanation: Ethanol is a functional isomers of dimethyl ether, as both have the same molecular formula CH3CH2OH

Correct answer: Dimethyl ether
  • A. 2-butene
  • B. 2-butyne
  • C. 2-butanol
  • D. butanal

Explanation: 2-butene is the only compound among the options that has a carbon-carbon double bond, which allows for restricted rotation, giving rise to…

Correct answer: 2-butene
  • A. Stereoisomerism
  • B. Structural isomerism
  • C. Functional group isomerism
  • D. Position isomerism

Explanation: Geometric isomerism is a type of stereoisomerism.The isomers in which the order of atom binding is the same,but the arrangement of atoms…

Correct answer: Stereoisomerism
  • A. Opposite
  • B. Same
  • C. None of these
  • D. Center

Explanation: In the cis isomer two, "X" and "Y" groups lie on the same side of double bond.

Correct answer: Same
  • A. Same
  • B. Identical
  • C. Different
  • D. None of these

Explanation: The necessary and sufficient condition for a compound to exhibit geometric isomerism is that the two groups attached to the same carbon…

Correct answer: Different