Free Functional Groups MCQs with Answers

49 Functional Groups MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Functional groups are specific atoms or atom groups that determine the characteristic reactions and properties of organic compounds. Coverage includes alkenes, alkynes, halo, hydroxyl, ether, carbonyl, carboxyl, ester, amino and nitro groups, together with their structures, nomenclature and related homologous series.

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49 questions · page 1 of 3

Moderate
  • A. a hydroxyl group
  • B. a carbonyl group at the end of the chain, written CHO
  • C. a carboxyl group
  • D. a carbonyl group between two carbon atoms

Explanation: In an aldehyde the carbonyl carbon carries at least one hydrogen and so must be terminal, whereas in a ketone the same carbonyl group lies…

Correct answer: a carbonyl group at the end of the chain, written CHO
  • A. an alkane
  • B. an alkyne
  • C. an alcohol
  • D. an alkene or a cycloalkane

Explanation: Both an alkene, with one double bond, and a cycloalkane, with one ring, have two hydrogens fewer than the corresponding alkane, so they…

Correct answer: an alkene or a cycloalkane
  • A. COOH
  • B. CHO
  • C. OH
  • D. CO

Explanation: The carboxyl group combines a carbonyl and a hydroxyl on the same carbon atom, and this arrangement makes the hydrogen far more acidic…

Correct answer: COOH
Moderate
  • A. COOR, formed by replacing the acidic hydrogen of a carboxylic acid
  • B. OH attached to a benzene ring
  • C. NH2 attached to a carbon chain
  • D. a carbon to carbon triple bond

Explanation: An ester is formed when a carboxylic acid reacts with an alcohol, water being eliminated, and the resulting group is responsible for the…

Correct answer: COOR, formed by replacing the acidic hydrogen of a carboxylic acid
  • A. Methane
  • B. Ethanol
  • C. Acetic acid
  • D. Urea

Explanation: Heating ammonium cyanate causes rearrangement into urea, NH2CONH2, an organic compound containing a carbonyl group bonded to two amino…

Correct answer: Urea
  • A. Sodium hexadecanoate
  • B. Sodium octadecanoate
  • C. Sodium pentadecanoate
  • D. Both A & B

Explanation: Sodium hexadecanoate and sodium octadecanoate are soaps whose anions form insoluble calcium and magnesium salts, producing curdy scum in…

Correct answer: Both A & B
  • A. Bromine
  • B. Fluorine
  • C. Chlorine
  • D. Sulphur

Explanation: Ethyl mercaptan, CH3CH2SH, contains a thiol group with sulfur, so sulfur gives the compound its characteristic odour.

Correct answer: Sulphur
  • A. Methanamide
  • B. Methanoylamine
  • C. Aminoethanol
  • D. Formanide

Explanation: HCONH2 is the amide derived from methanoic acid by replacing the acid hydroxyl group with NH2.

Correct answer: Methanamide
  • A. Nitrogen gas
  • B. NH3
  • C. CN‾
  • D. NO

Explanation: In Lassaigne's sodium-fusion test, nitrogen in an organic compound is converted into sodium cyanide, NaCN.

Correct answer: CN‾
  • A. Cl
  • B. N2
  • C. CO2
  • D. CO

Explanation: The Beilstein test detects halogens in an organic compound by producing a volatile copper halide that gives a coloured flame.

Correct answer: Cl
  • A. ethylene glycol
  • B. glycerol
  • C. picric acid
  • D. ethyl acetate

Explanation: Ethyl acetate, CH3COOCH2CH3, is an ester and contains no hydroxyl, or -OH, group.

Correct answer: ethyl acetate
  • A. CH3NH2
  • B. CH3NO2
  • C. CH3CN
  • D. CH2 = CH - CN

Explanation: Methyl cyanide is acetonitrile, whose condensed formula is CH3CN; the -CN group is the nitrile functional group.

Correct answer: CH3CN
  • A. CH2Cl2
  • B. CH3Cl
  • C. CHCl3
  • D. CCl4

Explanation: Chloroform is trichloromethane, so three hydrogen atoms of methane are replaced by chlorine and its formula is CHCl3.

Correct answer: CHCl3
  • A. Grignard reagent
  • B. Metallic alkyl halide
  • C. Both A & B
  • D. Alkyl

Explanation: R-Mg-Br is an organomagnesium halide called a Grignard reagent, and it contains an alkyl group directly bonded to a metal, so it is also…

Correct answer: Both A & B
  • A. Imino group
  • B. Amino group
  • C. Amide group
  • D. Nitro group

Explanation: Aniline is aminobenzene, with an -NH2 group directly attached to the benzene ring, so it contains an amino group.

Correct answer: Amino group
  • A. Hydrogen
  • B. Oxygen
  • C. Sulphur
  • D. OH

Explanation: Benzene sulphonic acid has the structure C6H5SO3H, so the benzene carbon is directly bonded to the sulphur atom of the sulphonic group.

Correct answer: Sulphur
  • A. radical
  • B. hydrocarbon
  • C. functional group
  • D. ion

Explanation: A functional group is a specific atom or group of atoms that gives an organic compound its characteristic chemical reactions and…

Correct answer: functional group
  • A. OH
  • B. R-CO-R
  • C. R-O-R
  • D. R-COOH

Explanation: An ether contains an oxygen atom single-bonded to two carbon-containing groups, represented generally as R-O-R.

Correct answer: R-O-R
  • A. R-NH2
  • B. RCONH2
  • C. R - NH - R
  • D. C6H5NH2

Explanation: An amide contains a carbonyl group directly attached to nitrogen, represented by RCONH2.

Correct answer: RCONH2
  • A. They are usually volatile liquids
  • B. Show weak hydrogen bonding
  • C. They are highly flammable with low boiling points
  • D. It is poisonous and is used as a disinfectant in hospitals

Explanation: Ethers are generally volatile liquids with low boiling points because they cannot form strong intermolecular hydrogen bonds.

Correct answer: It is poisonous and is used as a disinfectant in hospitals

Functional Groups MCQs: common questions

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