The functional group present in an aldehyde is

  • A. a hydroxyl group
  • B. a carbonyl group at the end of the chain, written CHO
  • C. a carboxyl group
  • D. a carbonyl group between two carbon atoms

Explanation

In an aldehyde the carbonyl carbon carries at least one hydrogen and so must be terminal, whereas in a ketone the same carbonyl group lies between two carbon atoms. This structural difference is why aldehydes are readily oxidised to carboxylic acids and give a positive test with Tollens reagent while ketones do not. The carboxyl group of an acid combines a carbonyl and a hydroxyl on the same carbon.

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