Free Fundamental Principles of Organic Chemistry MCQs with Answers

536 Fundamental Principles of Organic Chemistry MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Organic chemistry begins with carbon compounds classified by carbon skeleton, saturation and functional group. Work includes identifying groups such as hydroxyl, carbonyl, carboxyl and amino, applying basic nomenclature, and distinguishing structural, geometric and optical isomers, where the same molecular formula does not necessarily mean the same structure or properties.

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536 questions · page 14 of 27

  • A. CH2
  • B. C2H4
  • C. C2H6
  • D. C4H8

Explanation: For CH2,C2H4 and C3H4 and C3H6C = 85% H = 15%

Correct answer: C2H6
  • A. 5 moles of C
  • B. 8 moles of C
  • C. 4 moles of C
  • D. 13 moles of C

Explanation: Explanation for this question will be added soon!

Correct answer: 4 moles of C
  • A. 20
  • B. 40
  • C. 50
  • D. 60

Explanation: Volume= 5.6 liter. Mass= 10 grams. Volume/22.4 = mole 5.6 /22.4= 0.25 moles. Mole = Mass / Mr Mr = Mass / Mole = 10 / 0.25 = 40.

Correct answer: 40
  • A. 12 times
  • B. 1/12th
  • C. 1/6th
  • D. 6 times

Explanation: The atomic mass unit (AMU or amu) of an element is a measure of its atomic mass.

Correct answer: 1/12th
  • A. Aniline
  • B. Cyclohexanol
  • C. Cyclobutane
  • D. Neopentane

Explanation: Aniline is an aromatic compound. While B and C are alicyclic, while D is branched aliphatic organic compound.

Correct answer: Aniline
  • A. Asymmetry
  • B. Resonance
  • C. Rotation around single bond
  • D. Restricted rotation around doubled bond

Explanation: Alkanes do not show geometrical isomerism due to free rotation around single bond.

Correct answer: Rotation around single bond
  • A. Alkanes
  • B. Alkene
  • C. Alkynes
  • D. Alcohol

Explanation: In alkanes there is no functional group, therefore it can not show positional isomerism

Correct answer: Alkanes
  • A. Number of carbon atoms
  • B. Number of hydroxyl groups
  • C. Position of hydroxyl groups
  • D. All of these

Explanation: The correct answer is Option D: All of these. Glycols and glycerols can be differentiated based on the number of carbon atoms (glycol has…

Correct answer: All of these
  • A. CH3-CH2-OH
  • B. CH3COOH
  • C. CH3-O-CH3
  • D. CH3-CH2-Br

Explanation: Alcohols have OH-group as a functional group.

Correct answer: CH3-CH2-OH
  • A. CnH2n and CnH2n-2
  • B. CnH2n-2 and CnH2n+2
  • C. CnH2n+2
  • D. CnH2n and CnH2n+2

Explanation: Propene is alkene which has general formula CnH2n and Propyne is alkyne with general formula CnH2n-2

Correct answer: CnH2n and CnH2n-2
  • A. 1-Chloro-2-methylbutane
  • B. Iso-butyl chloride
  • C. 1-Chloro-2-methylpropane
  • D. 2-Chloro-2-methyl propane

Explanation: Priority is given to functional group in nomenclature

Correct answer: 1-Chloro-2-methylpropane
  • A. -COOH
  • B. -CHO
  • C. -C=O
  • D. -COOR

Explanation: Option D is correct because -COOR- is the functional group for Esters. All other options do not represent Ester's functional group.

Correct answer: -COOR
  • A. Hydrocarbons
  • B. Derivatives of hydrocarbons
  • C. Both A and B
  • D. Neither A nor B

Explanation: Classes of organic compounds contains , hydrocarbons as well as there derivatives.. Hence , C is the correct option.

Correct answer: Both A and B
  • A. Structural isomers
  • B. Stereoisomers
  • C. Enantiomers
  • D. Diasteromers

Explanation: Both of the stated compounds are only structural isomers of each other and are optically inactive.

Correct answer: Structural isomers
  • A. Anthracene
  • B. Naphthalene
  • C. Phenol
  • D. All of these

Explanation: Aromatic hydrocarbons containing two or more benzene rings in their molecules are called Polycyclic Aromatic Hydrocarbons.

Correct answer: All of these
  • A. sp2
  • B. sp3
  • C. sp
  • D. dsp2

Explanation: Each carbon in benzene has 3 σ-bonds and 1 π-bond. 3 σ-bonds means that there are 3 sp2 hybrid orbitals for each carbon.

Correct answer: sp2
  • A. Tetra-methyl lead
  • B. Tetra-ethyl lead
  • C. Isooctane
  • D. All of these

Explanation: The correct answer is 'All of these' because tetra-methyl lead, tetra-ethyl lead, and isooctane all exhibit antiknock properties.

Correct answer: All of these
  • A. Position isomers
  • B. Chain isomers
  • C. Functional group isomers
  • D. Metamers

Explanation: Positional isomers are compounds that have the same molecular formula and functional groups but differ in the position of the functional…

Correct answer: Position isomers
  • A. Octahedral
  • B. Tetrahedral
  • C. Trigonal planar
  • D. Square planar

Explanation: The geometry of butane is tetrahedral. This means that each carbon atom in butane is bonded to four other atoms, and the angles between…

Correct answer: Tetrahedral
  • A. Rotation around a double bond
  • B. Restriction of rotation around a single bond
  • C. Restriction of rotation around a double bond
  • D. Due to double bond

Explanation: The rotation of two carbon atoms joined by a double bond could happen only if the π bond breaks.This ordinarily costs too much energy…

Correct answer: Restriction of rotation around a double bond