All Free Chemistry MCQs with Answers

Every Chemistry question in the bank, across all chapters, each with the correct answer and a written explanation. Free and unlimited, with no account needed.

13,720 questions · page 528 of 686

  • A. Q
  • B. Q - W
  • C. Q / W
  • D. Q + Q

Explanation: The correct answer is Q - W, which corresponds to the change in internal energy (∆E) of a system.

Correct answer: Q - W
  • A. ∆Hfusion is positive only
  • B. ∆H aq is positive only
  • C. ∆Hn is negative only
  • D. ∆Hsoln is negative only

Explanation: The enthalpy of solution (∆Hsoln) can be either positive or negative. It is incorrect to state it is negative only, as dissolution can be…

Correct answer: ∆Hsoln is negative only
  • A. -217.4 kJ
  • B. -119 kJ
  • C. +217.4 kJ
  • D. +119 kJ

Explanation: To find the heat of formation of PCl5, we need to add the enthalpy changes of the given reactions.

Correct answer: +119 kJ
  • A. (y - 2x)
  • B. (x + y)
  • C. (2x -y)
  • D. 2x/y

Explanation: Reverse the second reaction and change the sign of its enthalpy change: SO3(g) + y kJ → SO2(g) + 1/2 O2(g) Multiply the first reaction by…

Correct answer: (2x -y)
  • A. 4
  • B. 27
  • C. 4/27
  • D. 1/27

Explanation: To find the equilibrium constant Kp for the reaction NH4COONH2(s) <-> 2NH3(g) + CO2(g), we use the formula Kp = PNH3^2 * PCO2 where P…

Correct answer: 4
  • A. Tf > Ti for reversible process but Tf = Ti for irreversible process.
  • B. (Tf)rev = (Tf)irrev
  • C. Tf = Ti for both reversible and irreversible processes
  • D. (Tf)irrev > (Tf)rev

Explanation: In an isolated system, the expansion of an ideal gas occurs adiabatically, meaning no heat is exchanged with the surroundings (q = 0).

Correct answer: (Tf)irrev > (Tf)rev
  • A. the internal energy changes in all processes
  • B. internal energy and entropy are state functions
  • C. the change in entropy can never be 0
  • D. the work done an adiabatic process is always 0

Explanation: This statement is generally true. State functions depend only on the current state of a system (its thermodynamic state), not on the path…

Correct answer: internal energy and entropy are state functions
  • A. Entropy
  • B. Internal energy
  • C. Volume
  • D. Density

Explanation: Density is not a state variable of thermodynamics because it depends on both the state variables of volume and mass.

Correct answer: Density
  • A. Amount of heat added to the system
  • B. Amount of heat rejected from the system
  • C. The temperature of the substance
  • D. Amount of the substance

Explanation: The change in entropy is defined as ΔS = ΔQ/T, where ΔQ is the heat transfer and T is the temperature.

Correct answer: Amount of the substance
  • A. Decreases
  • B. Increases
  • C. Remains the same
  • D. Both A and B

Explanation: The energy of the universe increases because energy never flows uphill spontaneously.

Correct answer: Increases
  • A. Boiling point
  • B. Molarity
  • C. Freezing point
  • D. All of the above

Explanation: An intensive property does not change with the size or amount of the sample; it is inherent to the substance itself.

Correct answer: All of the above
  • A. Double of the original value
  • B. Half of the original value
  • C. Remain the same as the original value
  • D. One-fourth of the original value
  • E. Heat of formation

Explanation: Thermodynamic properties can be divided into two general classes, intensive and extensive properties.

Correct answer: Half of the original value
  • A. Temperature
  • B. Volume
  • C. Quantity
  • D. Pressure

Explanation: Mass and volume are examples of extensive properties. An intensive property is a property of matter that depends only on the type of…

Correct answer: Quantity
  • A. 2
  • B. 6
  • C. 4
  • D. 8

Explanation: The coordination number of a transition metal complex is defined as the number of ligands attached to the central metal atom/ion.

Correct answer: 6
  • A. 0
  • B. 2
  • C. 4
  • D. 6

Explanation: CO is a neutral monodentate ligand. The charge on the overall complex is zero.

Correct answer: 0
  • A. outer transition elements
  • B. inner transition elements
  • C. typical transition elements
  • D. Transition elements

Explanation: Transition elements are those elements that have partially filled d orbitals in their ground state or common oxidation states.

Correct answer: Transition elements
  • A. increases
  • B. decreases
  • C. remain same
  • D. no regular trend

Explanation: This is generally correct. As you move across the 3d series from left to right, there is an increase in the atomic number.

Correct answer: increases
  • A. orbitals of f sub shell
  • B. orbitals of d sub shell
  • C. both a and b
  • D. Orbitals of p-subshell

Explanation: Transition elements are characterized by the partially filled d-subshell in their electronic configuration.

Correct answer: both a and b
  • A. anion
  • B. cation
  • C. ligand
  • D. acid

Explanation: Ligands are molecules or ions that donate electrons to a central metal atom to form a coordination complex.

Correct answer: ligand
  • A. Ammine
  • B. oxalato
  • C. carbonyl
  • D. cyano

Explanation: A chelate is a complex in which a central metal ion is bonded to the same ligand at multiple points.The oxalate ion (C₂O₄²⁻) has two…

Correct answer: oxalato