All Free Chemistry MCQs with Answers

Every Chemistry question in the bank, across all chapters, each with the correct answer and a written explanation. Free and unlimited, with no account needed.

13,720 questions · page 1 of 686

  • A. Neutrons in the nucleus
  • B. Protons in the nucleus
  • C. Protons and neutrons combined
  • D. Electron shells

Explanation: The atomic number equals the number of protons in the nucleus and determines the identity of the element.

Correct answer: Protons in the nucleus
  • A. Covalent bond
  • B. Ionic bond
  • C. Metallic bond
  • D. Hydrogen bond

Explanation: Sodium transfers its single valence electron to chlorine, producing Na⁺ and Cl⁻ ions held together by electrostatic attraction — an ionic…

Correct answer: Ionic bond
  • A. shape of orbital
  • B. main energy level and distance from the nucleus
  • C. orientation of the orbital in space
  • D. direction of spin

Explanation: The principal quantum number sets the shell, and therefore the main energy level and the average distance of the electron from the…

Correct answer: main energy level and distance from the nucleus
  • A. Three
  • B. Five
  • C. Seven
  • D. Nine

Explanation: For the d subshell l equals 2, so m runs from minus 2 to plus 2, giving five values and therefore five orbitals.

Correct answer: Five
  • A. n = 2, l = 1, m = 0
  • B. n = 3, l = 2, m = -2
  • C. n = 2, l = 2, m = 1
  • D. n = 4, l = 0, m = 0

Explanation: The azimuthal quantum number l is restricted to values from 0 up to n minus 1, so with n equal to 2 the only allowed values of l are 0 and…

Correct answer: n = 2, l = 2, m = 1
  • A. 8
  • B. 10
  • C. 18
  • D. 32

Explanation: The capacity of a shell is 2n squared, so for n equal to 3 that is 2 times 9, which is 18.

Correct answer: 18
  • A. spherical
  • B. dumbbell shaped
  • C. doughnut shaped
  • D. tetrahedral

Explanation: A p orbital has two lobes on opposite sides of the nucleus with a node at the nucleus itself, giving the familiar dumbbell shape, and the…

Correct answer: dumbbell shaped
Moderate
  • A. pair up in the first orbital before entering the next
  • B. occupy separate orbitals with parallel spins before pairing
  • C. occupy the orbital of highest energy first
  • D. always pair with opposite spins immediately

Explanation: Electrons repel one another, so they spread across orbitals of equal energy singly and with parallel spins before any orbital takes a…

Correct answer: occupy separate orbitals with parallel spins before pairing
  • A. [Ar] 3d4 4s2
  • B. [Ar] 3d5 4s1
  • C. [Ar] 3d6 4s0
  • D. [Ar] 3d3 4s3

Explanation: Chromium promotes one 4s electron into the 3d subshell because a half filled d5 configuration alongside a half filled 4s is more stable…

Correct answer: [Ar] 3d5 4s1
Fairly easy
  • A. continuously in any amount
  • B. in discrete packets whose energy is proportional to frequency
  • C. only as heat
  • D. in packets whose energy is proportional to wavelength

Explanation: Planck proposed that radiation is emitted in quanta of energy E equal to h times the frequency, where h is Planck's constant.

Correct answer: in discrete packets whose energy is proportional to frequency
Hard
  • A. n = 1
  • B. n = 2
  • C. n = 3
  • D. n = 4

Explanation: The Balmer series arises from transitions ending at n equal to 2 and it is the only hydrogen series that falls in the visible region…

Correct answer: n = 2
Fairly easy
  • A. electrons can have any energy value
  • B. electron energies inside an atom are quantised
  • C. the nucleus contains neutrons
  • D. hydrogen atoms contain more than one electron

Explanation: A hot gas emits light only at particular wavelengths, producing separate bright lines instead of a continuous band, and each line…

Correct answer: electron energies inside an atom are quantised
  • A. the cathode of the discharge tube
  • B. the residual gas atoms losing electrons in a discharge tube
  • C. the radioactive decay of uranium
  • D. the anode metal evaporating

Explanation: Goldstein observed that cathode rays travelling through a perforated cathode knocked electrons off the residual gas atoms, leaving…

Correct answer: the residual gas atoms losing electrons in a discharge tube
Hard
  • A. 4p
  • B. 3d
  • C. 4d
  • D. 5s

Explanation: Orbitals fill in order of increasing n plus l, and where that sum ties the lower n goes first.

Correct answer: 3d
  • A. directly proportional to its pressure
  • B. inversely proportional to its pressure
  • C. independent of its pressure
  • D. proportional to the square of its pressure

Explanation: Boyle's law gives PV equal to a constant, so doubling the pressure halves the volume.

Correct answer: inversely proportional to its pressure
Hard
  • A. 200 cm3
  • B. 250 cm3
  • C. 1250 cm3
  • D. 100 cm3

Explanation: Applying P1V1 equal to P2V2 gives V2 equal to 2 times 500 divided by 5, which is 200 cm3.

Correct answer: 200 cm3
  • A. 25 degrees C and 1 atm
  • B. 0 degrees C and 1 atm
  • C. 0 K and 1 atm
  • D. 25 degrees C and 760 mm of mercury above atmospheric

Explanation: STP is 273.15 K, which is 0 degrees Celsius, at a pressure of 1 atmosphere or 760 mm of mercury.

Correct answer: 0 degrees C and 1 atm
Very hard
  • A. 0 degrees C
  • B. -100 degrees C
  • C. -273.15 degrees C
  • D. -373 degrees C

Explanation: Extrapolating the straight line of volume against temperature backwards, every gas reaches zero volume at minus 273.15 degrees Celsius…

Correct answer: -273.15 degrees C
  • A. 54 degrees C
  • B. 300 degrees C
  • C. 327 degrees C
  • D. 600 degrees C

Explanation: Charles's law must be applied in kelvin, so the initial temperature is 27 plus 273, which is 300 K.

Correct answer: 327 degrees C
Hard
  • A. Gas molecules attract one another strongly
  • B. The volume of the molecules themselves is negligible compared with the volume of the container
  • C. Collisions between molecules lose energy as heat
  • D. The molecules all move at the same speed

Explanation: The ideal model treats molecules as point masses with negligible volume and no intermolecular forces, colliding perfectly elastically so…

Correct answer: The volume of the molecules themselves is negligible compared with the volume of the container