An ideal gas is allowed to expand both reversibly and irreversibly in an isolated system. If Ti is the initial temperature and Tf is the final temperature, which of the following statements is correct?

Correct answer: D. (Tf)irrev > (Tf)rev

  • A. Tf > Ti for reversible process but Tf = Ti for irreversible process.
  • B. (Tf)rev = (Tf)irrev
  • C. Tf = Ti for both reversible and irreversible processes
  • D. (Tf)irrev > (Tf)rev

Explanation

In an isolated system, the expansion of an ideal gas occurs adiabatically, meaning no heat is exchanged with the surroundings (q = 0). For reversible processes, the work done is maximized, resulting in a greater decrease in internal energy and thus a lower final temperature compared to irreversible processes. Therefore, the final temperature after an irreversible expansion is higher than that after a reversible expansion.Option A is incorrect because the temperature change is not the same for reversible and irreversible processes. Option B is incorrect because the final temperatures are not equal due to different efficiencies in work done. Option C is incorrect because the expansion process induces a temperature change.

Written and checked by , M.Phil ChemistryLast updated
Report an error

The more specific you are, the faster it gets fixed. A source beats an opinion.

Prefer email? [email protected]

About Thermochemistry and Energetics of Chemical Reactions

Thermochemistry measures energy changes in chemical reactions and distinguishes exothermic from endothermic processes. Work covers systems, surroundings and state functions, internal energy, the first law of thermodynamics, enthalpy and Hess's law, including the sign conventions used when heat enters or leaves a system.

Practise Thermochemistry and Energetics of Chemical Reactions

728 free Thermochemistry and Energetics of Chemical Reactions MCQs from Chemistry, each with the correct answer and an explanation. Unlimited attempts, no account needed.

Discussion

Stuck on an option, or know a faster way to get there? Ask or explain it here.

No comments yet. Be the first to explain this one.

Exams that ask Chemistry questions like this

Chemistry is on 14 papers prepared for on TestUstad, and all of them draw the same bank, so this question is worth knowing for every one of them.

More Thermochemistry and Energetics of Chemical Reactions questions