Free Alkanes MCQs with Answers

127 Alkanes MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Alkanes are saturated hydrocarbons containing only carbon-carbon and carbon-hydrogen single bonds, with the general formula CnH2n+2 for open chains. Their structure, isomerism, IUPAC nomenclature, physical properties, combustion, free-radical halogenation and conformations are covered, including the difference between substitution in alkanes and addition in unsaturated hydrocarbons.

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127 questions · page 3 of 7

  • A. Isomerization
  • B. Adding (C2H5)4 Pb
  • C. Adding (CH3)4 Pb
  • D. All

Explanation: Octane number can be increased by converting straight-chain hydrocarbons into branched isomers and by using antiknock additives such as…

Correct answer: All
  • A. PbCl2
  • B. (C2H5)4 Pb
  • C. (C2H5)2 Pb
  • D. all of the above

Explanation: Tetraethyl lead, (C2H5)4Pb, was historically added to petrol to increase octane rating and reduce engine knocking.

Correct answer: (C2H5)4 Pb
  • A. knocking
  • B. reforming
  • C. cracking
  • D. a and c

Explanation: Knocking is the metallic sound caused by abnormal, premature or uncontrolled ignition of the fuel-air mixture in an engine.

Correct answer: knocking
  • A. polymerization
  • B. pyrolysis
  • C. isomerism
  • D. no such process occurs

Explanation: Pyrolysis is the thermal decomposition of a large molecule into smaller molecules in the absence of oxygen; hydrocarbon cracking is a…

Correct answer: pyrolysis
  • A. n. butane
  • B. Ethanol
  • C. Ethane
  • D. Diethy1 ether

Explanation: Reduction replaces the chlorine atom in ethyl chloride, CH3CH2Cl, with hydrogen: CH3CH2Cl + 2[H] -> CH3CH3 + HCl.

Correct answer: Ethane
  • A. Alkenes
  • B. Alkynes
  • C. Alkanes
  • D. Benzene

Explanation: Both alkenes and cycloalkanes have general formula CnH2n.

Correct answer: Alkenes
  • A. Butane
  • B. Propane
  • C. Pentane
  • D. Hexane

Explanation: In the Wurtz reaction, two alkyl halides react with sodium to form a higher alkane.

Correct answer: Propane
  • A. Cannizaro's reaction
  • B. Kolbe's reaction
  • C. Sabatier & Senderen's reaction
  • D. Wurtz reaction

Explanation: Option D is correct as the Wurtz reaction is an organic chemical coupling reaction wherein sodium metal is reacted with two alkyl halides…

Correct answer: Wurtz reaction
  • A. 3,3 4- trimethyl hexane
  • B. 1,1,2- trimethyl ethane
  • C. 2,2-dimethyl propane
  • D. 2-ethyl,1-methylethane

Explanation: To name this first identity the longest carbon chain is 6-carbon long. Hence the name should include hexane, which is A.

Correct answer: 3,3 4- trimethyl hexane
  • A. Mixture of SiO2 and Ni
  • B. Mixture of Pt and Cu
  • C. Mixture of Fe and MgO
  • D. Mixture of SiO2 and Al2O3

Explanation: A typical catalyst used for this purpose is a mixture of silica (SiO2) and alumina (AI2O3). So this is correct answer.

Correct answer: Mixture of SiO2 and Al2O3
  • A. A: Thermal
  • B. B: Catalytic
  • C. C: Steam
  • D. D: Radiations

Explanation: The correct answer is Catalytic cracking, which is a preferred method for producing higher quality gasoline.

Correct answer: B: Catalytic
  • A. Two hydrogen atoms
  • B. Three hydrogen atoms
  • C. One hydrogen atom
  • D. No hydrogen atom

Explanation: The central (tertiary) carbon atom in t-butyl alcohol is bonded to three methyl groups (-CH3) and a hydroxyl group (-OH).

Correct answer: No hydrogen atom
  • A. 2,2-Dimethyl pentane
  • B. 2,3-Dimethyl pentane
  • C. 2,2-Dimethyl propane
  • D. 2,2-Dimethyl butane

Explanation: 2,2-Dimethyl butane is called neohexane not neopentane.

Correct answer: 2,2-Dimethyl propane
  • A. 2-Ethyl-3-methyl pentane
  • B. 3-Ethyl-2-methyl pentane
  • C. 3-Methyl cyclohexane
  • D. 3-Ethyl-4-methyl pentane

Explanation: According to IUPAC nomenclature Number the longest chain, beginning with the end nearest a branch.

Correct answer: 3-Ethyl-2-methyl pentane
  • A. 7
  • B. 6
  • C. 5
  • D. 4

Explanation: Hexane (C6H14) is an alkane with six carbon atoms. Alkanes are hydrocarbons with only single bonds between carbon atoms.

Correct answer: 5
  • A. 3-Ethyl-2-methyl pentane.
  • B. 2,3-Dimethylpentane.
  • C. 2,2,4-Trimethylhexane.
  • D. 2,3,4-Trimethylhexane

Explanation: The correct name of the compound 3,5,5-trimethylhexane indicates that there are three methyl groups at positions 3, 5, and 5 on the hexane…

Correct answer: 2,2,4-Trimethylhexane.
  • A. Decrease boiling point
  • B. Prevent overheating
  • C. Prevent fuel from freezing
  • D. Prevent knocking

Explanation: Tetraethyllead was historically used as an anti-knock agent in gasoline.

Correct answer: Prevent knocking
  • A. Cracking
  • B. Reforming
  • C. Decomposition
  • D. Isomerisation

Explanation: Option A) Cracking involves breaking down large hydrocarbons into smaller ones and does not necessarily result in a higher octane…

Correct answer: Reforming
  • A. Ethane
  • B. Propane
  • C. Butene
  • D. Isobutane

Explanation: When n-butane is heated in the presence of AlCl3/HCl, it undergoes a rearrangement reaction to form Isobutane.Option A (Ethane), Option B…

Correct answer: Isobutane
  • A. 3-ethyl-2,2,4-trimethylpentane
  • B. 4-ethyl-2,2,4-trimethylpentane
  • C. 5-ethyl-2,2,4-trimethylpentane
  • D. 2-ethyl-2,2,4-trimethylpentane
  • E. 1-ethyl-2,2,4-trimethylpentane

Explanation: The IUPAC name for the given compound (CH3)2-CH-CH(C2H5)-C(CH3)3 is "3-ethyl-2,2,4-trimethylpentane." Here's how the name is derived:1.

Correct answer: 3-ethyl-2,2,4-trimethylpentane