Free Chemical Reaction Engineering MCQs with Answers

395 Chemical Reaction Engineering MCQs from Chemical Engineering, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

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395 questions · page 17 of 20

  • A. 0
  • B. > 150
  • C. < 2100
  • D. ∞

Explanation: Perfect mixing corresponds to maximum axial dispersion, so the dispersion number approaches infinity.

Correct answer: ∞
  • A. Is same as heat of reaction at constant pressure
  • B. Is the minimum energy which the molecules must have before the reaction can take place
  • C. Varies as fifth power of the temperature
  • D. Both B. and C.

Explanation: Activation energy is the energy barrier that reacting molecules must overcome for reaction to occur.

Correct answer: Is the minimum energy which the molecules must have before the reaction can take place
  • A. Same in both the reactors
  • B. Higher in CSTR
  • C. Higher in P.F. reactor
  • D. Data insufficient; can't be predicted

Explanation: For a normal positive-order reaction, the plug-flow reactor maintains a higher reactant concentration over much of its length than the…

Correct answer: Higher in P.F. reactor
  • A. Usually equal to the residence time
  • B. The reciprocal of the space velocity
  • C. A measure of its capacity
  • D. Both A. and B.

Explanation: Space time is reactor volume divided by inlet volumetric flow rate, and it is the reciprocal of space velocity.

Correct answer: Both A. and B.
  • A. Exothermic
  • B. Autocatalytic
  • C. Endothermic
  • D. Autothermal

Explanation: In an autocatalytic reaction, the product promotes the reaction and partly offsets the decrease in reactant concentration as conversion…

Correct answer: Autocatalytic
  • A. Always equal to the total stoichiometric number of reactants
  • B. An experimentally determined quantity
  • C. Never fractional
  • D. None of these

Explanation: Reaction order comes from the experimentally determined rate law, not directly from the stoichiometric equation.

Correct answer: An experimentally determined quantity
  • A. Increased temperature reduces the activation energy
  • B. Collision frequency increases
  • C. Fraction of molecules having threshold energy increases
  • D. Value of threshold energy decreases

Explanation: From the Arrhenius equation, increasing temperature raises the fraction of molecules whose energy exceeds the activation or threshold…

Correct answer: Fraction of molecules having threshold energy increases
  • A. The composition of reactants remains constant along a flow path
  • B. The conversion of the reactant varies from point to point along a flow path
  • C. There is no lateral mixing of fluid
  • D. There may be diffusion along the flow path

Explanation: In a plug-flow reactor, fluid elements move progressively downstream, so reactant conversion increases from point to point along the flow…

Correct answer: The conversion of the reactant varies from point to point along a flow path
  • A. Slurry
  • B. Plug flow
  • C. Homogeneous catalytic
  • D. None of these

Explanation: Hydrogenation of vegetable oils uses a finely divided solid catalyst suspended in the liquid oil, with hydrogen gas dispersed through the…

Correct answer: Slurry
  • A. Freundlich
  • B. Langmuir
  • C. Tempkin
  • D. None of these

Explanation: The BET equation extends the Langmuir monolayer adsorption concept to multilayer adsorption, allowing catalyst surface area to be…

Correct answer: Langmuir
  • A. First
  • B. Zero
  • C. Second
  • D. Third

Explanation: For a second-order reaction, the half-life is t₁/₂ = 1/(kC_A0), so it is inversely proportional to the initial concentration.

Correct answer: Second
  • A. V
  • B. V/n
  • C. V.n
  • D. 1/V

Explanation: PFR volumes in series add, and a series of ideal plug-flow sections behaves like one ideal PFR having the same total volume.

Correct answer: V
  • A. Linearly with time
  • B. Exponentially with time
  • C. Very abruptly towards the end of the reaction
  • D. Logarithmically with time

Explanation: Integrating the first-order rate law gives C_A = C_A0e⁻ᵏᵗ, so concentration falls exponentially rather than linearly with time.

Correct answer: Exponentially with time
  • A. None of the above
  • B. Reaction
  • C. External mass transfer
  • D. Diffusion within the pellet

Explanation: A much lower concentration at the pellet centre than at its surface indicates a steep internal concentration gradient.

Correct answer: Diffusion within the pellet
  • A. Ideal tubular-flow reactor
  • B. Batch reactor
  • C. Slurry reactor
  • D. CSTR

Explanation: Space time is based on reactor volume and inlet volumetric flow, making it convenient for sizing an ideal tubular-flow reactor.

Correct answer: Ideal tubular-flow reactor
  • A. Ideal plug flow
  • B. Dead zone
  • C. Bypass
  • D. Channelling

Explanation: A long tail means some material remains in the packed bed much longer than the main flow, which indicates stagnant or dead regions.

Correct answer: Dead zone
  • A. Inversely proportional to
  • B. Independent of
  • C. Proportional to
  • D. Proportional to the square of

Explanation: Without a chain mechanism, doubling the amount of catalyst doubles the available active surface and hence the overall rate, provided…

Correct answer: Proportional to
  • A. Decreases
  • B. Remains unchanged
  • C. Increases
  • D. Unpredictable from the data

Explanation: For an exothermic reversible reaction, increasing temperature shifts equilibrium toward the reactants, so the equilibrium conversion…

Correct answer: Decreases