Free Chemical Reaction Engineering MCQs with Answers

395 Chemical Reaction Engineering MCQs from Chemical Engineering, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

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395 questions · page 16 of 20

  • A. keff = k + kg
  • B. 1/keff = 1/k + 1/kg
  • C. keff = (kkg)1/2
  • D. keff = (k+ kg)/2

Explanation: External mass transfer and surface reaction act as consecutive resistances, so their reciprocal effective rate constants add: 1/k_eff =…

Correct answer: 1/keff = 1/k + 1/kg
  • A. XA/(1 - XA)Vs η
  • B. XA Vs ln η
  • C. XA Vs . η
  • D. XA(1 - XA)Vs η

Explanation: For a zero-order reaction in a CSTR, the design equation gives τ = C_A0 X_A/k, so conversion is directly proportional to residence time.

Correct answer: XA Vs . η
  • A. At the inlet
  • B. Averaged over the inlet and outlet
  • C. In the reactor
  • D. At the outlet

Explanation: The E-curve is the exit age distribution, so it describes the age distribution of fluid elements as they leave the reactor.

Correct answer: At the outlet
  • A. Solid catalysts
  • B. Darkness
  • C. Sunlight
  • D. Monochromatic radiation only

Explanation: Photochemical reactions require radiation to supply the energy needed to excite reacting molecules, and sunlight is the usual natural…

Correct answer: Sunlight
  • A. Data insufficient to calculate
  • B. 0.5
  • C. 0.425
  • D. 0.875

Explanation: After three half-lives, the unreacted fraction is (1/2)^3 = 1/8. Hence the conversion is 1 − 1/8 = 7/8 = 0.875.

Correct answer: 0.875
  • A. All A., B. and C.
  • B. Is the maximum feed rate per unit volume of reactor for a given conversion
  • C. Is a measure of the ease of the reaction
  • D. Describes the extensive operating characteristics of a tubular flow reactor

Explanation: Space velocity is the feed volumetric rate divided by reactor volume, so it indicates how rapidly a reactor volume of feed is processed.

Correct answer: All A., B. and C.
  • A. Less than
  • B. Equal to or more than
  • C. More than
  • D. Equal to

Explanation: Reaction occurs when molecular energy reaches or exceeds the activation-energy barrier.

Correct answer: Equal to or more than
  • A. Second
  • B. First
  • C. Zero
  • D. Fractional

Explanation: For a zero-order reaction, the rate is -rA = k, so the rate constant and reaction rate have identical units.

Correct answer: Zero
  • A. 60
  • B. 75
  • C. 90
  • D. 100

Explanation: For the first CSTR, X = kτ/(1 + kτ) = 0.5, giving kτ = 1. A second identical CSTR leaves CA/CA0 = 1/(1+kτ)^2 = 1/4, so the total…

Correct answer: 75
  • A. L √(K/D1)
  • B. ∞
  • C. 1
  • D. 1/[L√(K/D1)]

Explanation: When the Thiele modulus is large, diffusion strongly limits the reaction and only a thin region of catalyst is effectively used.

Correct answer: 1/[L√(K/D1)]
  • A. 1.0 to 10-8
  • B. 1.1 to 102
  • C. 0.1 to 0.9
  • D. None of these

Explanation: The steric factor accounts for the fraction of collisions having suitable molecular orientation and is usually much less than unity, with…

Correct answer: 1.0 to 10-8
  • A. k/2
  • B. ln k/2
  • C. ln 2/k
  • D. ln 0.5/k

Explanation: For a first-order irreversible reaction, CA/CA0 = e^-kt. At half-life CA/CA0 = 1/2, so kt = ln 2 and t1/2 = ln 2/k.

Correct answer: ln 2/k
  • A. Be more in CSTR than in PFR
  • B. Depend on the temperature
  • C. Be same in both cases
  • D. Be more in PFR than in CSTR

Explanation: For a first-order reaction, a PFR gives the highest conversion for a specified volume and flow rate because every fluid element…

Correct answer: Be more in PFR than in CSTR
  • A. None of the above
  • B. A step function
  • C. A ramp function
  • D. A Dirac delta function

Explanation: An ideal CSTR has an exponential exit age distribution, E(t) = (1/τ)e^(-t/τ), for t ≥ 0.

Correct answer: None of the above
  • A. May be lateral mixing of fluid
  • B. Both A. and B.
  • C. Should not be any mixing along the flow path
  • D. Neither A. nor B.

Explanation: The ideal PFR permits complete lateral or radial mixing but has no axial mixing between fluid elements moving along the reactor.

Correct answer: Both A. and B.
  • A. 0
  • B. 1
  • C. 2
  • D. 3

Explanation: Doubling concentration changes the rate by 2^n. Since the rate becomes four times larger, 2^n = 4 = 2^2, giving a second-order dependence…

Correct answer: 2
  • A. Temperature and pressure only
  • B. Temperature and composition only
  • C. Pressure and composition only
  • D. All temperature, pressure and composition

Explanation: A homogeneous reaction rate can depend on composition through concentrations or activities, on temperature through the rate constant, and…

Correct answer: All temperature, pressure and composition
  • A. Is always greater for plug-flow reactor than for the single CSTR of the same volume
  • B. Both A. and C. hold good
  • C. Decreases with increasing conversion
  • D. Statement in A. is wrong

Explanation: For a consecutive reaction in which an intermediate is the desired product, its relative yield generally falls as conversion increases…

Correct answer: Both A. and C. hold good
  • A. One of the reactants acts as a catalyst
  • B. Catalysts have very high selectivity
  • C. One of the products acts as a catalyst
  • D. No catalyst is used

Explanation: In an autocatalytic reaction, a product formed by the reaction accelerates the same reaction, creating self-catalysis.

Correct answer: One of the products acts as a catalyst