Moderate

A carbon, hydrogen and oxygen atoms containing organic compound (A), on reaction with an excess of CH3MgI, gives a gas (X) whose volume under STP conditions is found to be 89.6litre. Find the number of hydroxyl groups in the compound (A):

Correct answer: D. 4

  • A. 3
  • B. 5
  • C. 2
  • D. 4

Explanation

When a compound containing carbon, hydrogen, and oxygen atoms reacts with CH3MgI to produce a gas with a volume of 89.6 liters under STP conditions, it indicates the presence of 4 hydroxyl groups in the compound. The reaction involves the conversion of the oxygen in the compound to a hydroxyl group, leading to the formation of the gas. Options A, B, and C do not consider the correct stoichiometry of the reaction and the volume of gas produced, leading to incorrect answers.

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Hydrocarbons are studied through the structures and reactions of alkanes, alkenes, alkynes and aromatic compounds. Coverage includes free radical substitution in alkanes, electrophilic addition to carbon-carbon multiple bonds, benzene substitution, aromatic stability and the difference between addition reactions of alkenes and substitution reactions of benzene.

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