Free Transition Elements MCQs with Answers

531 Transition Elements MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Transition elements are identified by their partially filled d subshells in atoms or common ions. The topic covers the electronic structure of d-block elements, including the filling order of 4s and 3d orbitals, variable oxidation states and the distinction between transition elements and elements with completely filled d subshells.

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531 questions · page 9 of 27

  • A. [Cr(NH3)5SO4]Cl
  • B. [Co(NH3)4SO4]NO2
  • C. [Cr(NH3)5Cl]SO4
  • D. Both (A) and (C)

Explanation: A white precipitate with BaCl2 indicates the presence of free sulfate ions (SO42-) in the solution, which form insoluble BaSO4.

Correct answer: [Cr(NH3)5Cl]SO4
  • A. Potassium Alumino oxalate
  • B. Potassium trioxalatoaluminate(III)
  • C. Potassium aluminium(III) oxalate
  • D. Potassium trioxalato aluminate(VI)

Explanation: Following IUPAC nomenclature rules for coordination compounds: the cation (Potassium) is named first.

Correct answer: Potassium trioxalatoaluminate(III)
  • A. Tetraammine dihydroxo-platinum (IV) sulphate
  • B. Dihydroxo tetraammine-platinum (V) sulphate
  • C. Tetra-ammine dihydroxo-platinum (II) sulphate
  • D. Dihydroxo tetraammine-platinum (IV) sulphate

Explanation: As per the nomenclature of complex compounds, the correct name of given compound is "Tetraammine dihydroxo-platinum (IV) sulphate".

Correct answer: Tetraammine dihydroxo-platinum (IV) sulphate
  • A. All the elements except Scandium show +2 oxidation state
  • B. They show variable oxidation because of the involvement of the unpaired d-electrons in addition to s-electrons
  • C. Fe+3 ion is more stable than Fe+2 ion
  • D. First four elements in the highest oxidation state use all of the s and d electrons for bonding

Explanation: Many transition metals (except Sc) can show the +2 oxidation state, but not all do consistently.

Correct answer: All the elements except Scandium show +2 oxidation state
  • A. 4
  • B. 5
  • C. 6
  • D. 8

Explanation: The coordination number is the number of donor atoms directly bonded to the central metal ion. In this complex.

Correct answer: 6
  • A. Square planar
  • B. Trigonal bipyramidal
  • C. Triangular
  • D. Octahedral

Explanation: According to VSEPR theory and experimental evidence, the geometry that minimizes repulsion for a centralatom bonded to five other groups…

Correct answer: Trigonal bipyramidal
  • A. +2, +3, 0
  • B. +3, 0, +3
  • C. +2, +3, +4
  • D. 0, +3, +4

Explanation: For [Fe(CN)6]4-: Fe +6[-1]=-4. so Fe=+2. For [Co(NH3)3 (NO₂)3]: Co + 3(0) +3(-1)=0 so Co =+3. For [Ni(CO)4] Ni+4(0)=0 so Ni =0.

Correct answer: +2, +3, 0
  • A. Pyramidal
  • B. Square planar
  • C. Octahedral
  • D. Bipyramidal

Explanation: There are five carbonyl (CO) ligands attached with central atom (Fe), so coordination no is 5.

Correct answer: Bipyramidal
  • A. [Cu(H₂O6)]+2
  • B. [Pt(C₂O4)2]-2
  • C. [CuCl]-2
  • D. All have the same stability

Explanation: Complexes with polydentate ligands are more stable because they form chelate rings.

Correct answer: [Pt(C₂O4)2]-2
  • A. Estimating the concentration of iron
  • B. Measuring the concentration of CN-
  • C. Measuring the solid state magnetic moment.
  • D. Thermally decomposing the compound.

Explanation: The different electronic arrangements (Fe(II) vs Fe(III)) would result in a different number of unpaired d-electrons on the ron center.

Correct answer: Measuring the solid state magnetic moment.
  • A. Yellow, Green
  • B. Red, Yellow
  • C. Blue, Green
  • D. Red, Blue

Explanation: In [Ti(H₂O6)]+3, yellow light is absorbed while most of the red and blue lights are transmitted, therefore the solution of [Ti(H206)]+3…

Correct answer: Red, Blue
  • A. 1
  • B. 5
  • C. 4
  • D. Unpredictable

Explanation: In hexafluoroferrate(III), the iron is in the +3 oxidation state, giving it a d5 electron configuration.

Correct answer: 5
  • A. I- < H2O < NH3 < CN-
  • B. CN- < I- < H2O < NH3
  • C. CN- < NH3 < H2O < I-
  • D. NH3 < H2O < I- < CN-

Explanation: This question asks for the order of ligand strength according to the spectrochemical series arranges ligands based on their ability to…

Correct answer: I- < H2O < NH3 < CN-
  • A. 4
  • B. 2
  • C. 6
  • D. -4

Explanation: The coordination number refers to the number of atoms or ions bonded directly to the central atom in a complex ion or molecule.

Correct answer: 6
  • A. Zero
  • B. Two
  • C. Four
  • D. Six

Explanation: In [Co(NH3)6]+3, the coordination number of cobalt is six.

Correct answer: Six
  • A. Square planar
  • B. Tetrahedral
  • C. Octahedral
  • D. Linear

Explanation: Cu(NH3)4]4+ has a square planar structure.

Correct answer: Square planar
  • A. K4CrO4
  • B. K2Cr2O4
  • C. Cr2O6
  • D. CrCl3

Explanation: Chromium is in the +3 oxidation state. Each oxygen atom contributes -2, and there are two oxygen atoms per chromium atom, so in total, the…

Correct answer: K2Cr2O4
  • A. Oxidizing agent
  • B. Reducing agent
  • C. An Acid
  • D. A base

Explanation: Potassium dichromate is commonly used as an oxidizing agent in acidic medium.

Correct answer: Oxidizing agent
  • A. Fe
  • B. Ni
  • C. Co
  • D. All

Explanation: All of the elements mentioned (Fe, Ni, and Co) can form interstitial compounds under suitable conditions.

Correct answer: All
  • A. Aluminium
  • B. Copper
  • C. Carbon
  • D. Nickel

Explanation: Carbon is an essential element in steel production and is always present.

Correct answer: Carbon