Free Gases MCQs with Answers

443 Gases MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Gas behaviour is explained through the kinetic molecular theory and the relationships among pressure, volume and temperature. Work includes STP, Boyle's and Charles's laws, absolute zero, the ideal gas equation, and the distinction between ideal and real gases, especially the effects of intermolecular forces and molecular volume.

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443 questions · page 8 of 23

  • A. Boyle's law
  • B. Charles' law
  • C. Avogadro's law
  • D. Pascal's law

Explanation: Avogadro's Law has pressure and temperature as constant. This is when Volume is directly proportional to the number of moles.

Correct answer: Avogadro's law
  • A. 8.314Jmol-1K-1
  • B. 8.314 dm3 atm mol-lK-1
  • C. 0.0821dm3 atm mol-1 K-1
  • D. 0.0821Jmol-1K-1

Explanation: The universal gas constant value is 8.314 Jmol-1K-1.

Correct answer: 8.314Jmol-1K-1
  • A. Charles's law
  • B. Boyle's law
  • C. Avogadro's law
  • D. Pascal's law

Explanation: Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship.

Correct answer: Boyle's law
  • A. PV = nRT - n²A / V
  • B. PV = nRT + nbP
  • C. P = nRT / V - b
  • D. PV = nRT

Explanation: The van der Waals equation modifies the ideal gas law for real gases. The term 'a' corrects for the intermolecular forces of attraction…

Correct answer: PV = nRT - n²A / V
  • A. Less than 22.4L
  • B. Greater than 22.4L
  • C. Equal to 22.4L
  • D. None of these

Explanation: The compressibility factor Z=PV/RT. If Z > 1, it means the real volume is greater than the ideal volume.

Correct answer: Greater than 22.4L
  • A. √2v
  • B. 2v
  • C. v
  • D. 4v

Explanation: When the temperature of nitrogen gas (N₂) is doubled, the root mean square (rms) speed for the N₂ molecules increases by a factor of √2…

Correct answer: 2v
  • A. Increases on increasing temperature
  • B. Decreases on increasing temperature
  • C. Unchanged on changing temperature
  • D. Increases somewhere and decreases

Explanation: Mean free path is the average distance a molecule travels between collisions.

Correct answer: Unchanged on changing temperature
  • A. RT
  • B. a/Vm
  • C. b
  • D. Cannot be determined

Explanation: For a real gas obeying van der Waal's equation, a graph is plotted between PVm (y-axis) and P (x-axis), where Vm is molar volume.

Correct answer: RT
  • A. O2
  • B. SO2
  • C. NO
  • D. C4H10

Explanation: To determine the identity of gas X, we compare the given conditions for CO2 and gas X under the same pressure and temperature.

Correct answer: SO2
  • A. 6
  • B. 1/6
  • C. 2/3
  • D. 3/2

Explanation: This is the following solution:To determine the ratio of the pressures of gases A and B, let's use the ideal gas law equation: PV NRTThis…

Correct answer: 6
  • A. The constant 'a' is negligible and not 'b'
  • B. The constant 'b' is negligible and not 'a'
  • C. Both constants 'a' & 'b' are negligible
  • D. Both the constants 'a' & 'b' are not negligible

Explanation: At high pressures, molecules are close together, so the molecular volume (related to 'b') is no longer negligible.

Correct answer: The constant 'a' is negligible and not 'b'
  • A. 6.5
  • B. 2.23
  • C. 23.2
  • D. 85

Explanation: Given:Pressure (P) = 11 atmVolume (V) = 4 LNumber of moles (n) = 2 molesTemperature (T) = 300 KIdeal gas constant (R) = 0.0821 L atm /…

Correct answer: 6.5
  • A. 1 L
  • B. 0.1 L
  • C. 1.05 L
  • D. 1.50 L

Explanation: Using Charles's Law (V₁/T₁ = V₂/T₂), with temperatures in Kelvin. T₁ = 0°C = 273 K, and T₂ = 300°C = 573 K.

Correct answer: 1.05 L
  • A. The average kinetic energy of the gas molecules decreases
  • B. Gas molecules collide more frequently with the container walls
  • C. Gas molecules collide less frequently with the container walls
  • D. Gas molecules collide less energetically with the container walls

Explanation: According to the Kinetic Molecular Theory, as temperature increases, the average kinetic energy of gas molecules also increases.

Correct answer: Gas molecules collide more frequently with the container walls
  • A. 4
  • B. 2
  • C. 0.449
  • D. 1

Explanation: Step 1: Write the ratio expressionvrms (H2 ,50K) /vrms (O2 ,800K) = √TH2.Mo2/MH2.TO2 Step 2: Substitute values√50 X 0.032 / 0.002 X 800…

Correct answer: 1
  • A. P(Vm −b)=RT
  • B. (P+a/V2m)Vm =RT
  • C. PVm=RTP
  • D. (P−b)(Vm −a/V2m)=RT

Explanation: The Van der Waals equation simplifies by dropping the pressure correction term but keeping the volume correction term, which…

Correct answer: P(Vm −b)=RT
  • A. T(H2) = T(N2)
  • B. T(H2) > T(N2)
  • C. T(H2) < T(N2)
  • D. T(H2) = √7 T(N2)

Explanation: The rms velocity is v = √(3RT/M). Given v(H₂) = √7 v(N₂), we can set up the equation √(3RT(H₂)/M(H₂)) = √7 √(3RT(N₂)/M(N₂)).

Correct answer: T(H2) < T(N2)
  • A. Vm > 22.4 litres
  • B. Vm < 22.4 litres
  • C. Vm = 22.4 litres
  • D. Vm = 44.8 litres

Explanation: The compressibility factor Z = V / V . If Z is less than 1, it means the real molar volume (Vm) is less than the ideal molar volume.

Correct answer: Vm < 22.4 litres