Free Benzene and Aromatic Compounds MCQs with Answers

172 Benzene and Aromatic Compounds MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Benzene has a planar ring of delocalised π electrons, giving aromatic stability and equal carbon-carbon bond lengths. The topic covers resonance, electrophilic substitution reactions such as nitration, halogenation, sulphonation and Friedel-Crafts reactions, along with substituent effects and the distinction between substitution in benzene and addition in ordinary alkenes.

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172 questions · page 4 of 9

  • A. More π-bonds
  • B. Localized π-electrons
  • C. Delocalized π-electrons
  • D. More σ-bonds

Explanation: It undergoes resonance via π electron delocalization. Thus, the presence of 3 π bonds makes it less reactive and more stable than ethene…

Correct answer: Delocalized π-electrons
  • A. -OH
  • B. -OCH3
  • C. -CHO
  • D. -NH2

Explanation: OH and - NHCOCH 3 are ortho and para directing groups. These are also the electron donating groups and the attack of the incoming groups…

Correct answer: -OH
  • A. Phenol
  • B. Benzene
  • C. Nitrobenzene
  • D. Chlorobenzene

Explanation: Sulphonation of phenol at high temperature gives predominantly para isomer i.e. 4-phenol sulphonic acid.

Correct answer: Phenol
  • A. 3
  • B. 4
  • C. 5
  • D. 6

Explanation: In Kekule's structure, the carbon atoms in benzene are arranged in a hexagonal ring with each carbon atom is attached to two other carbon…

Correct answer: 5
  • A. Paraffins
  • B. Alkene
  • C. Benzene
  • D. Cyclohexane

Explanation: In the International Union of Pure and Applied Chemistry (IUPAC) system, aromatic hydrocarbons such as those above are named as…

Correct answer: Benzene
  • A. Atomic orbital treatment of benzene
  • B. Resonance method
  • C. Both (a) and (b)
  • D. None

Explanation: By virtue of resonance, the benzene molecule is stabilized; the pi electrons are delocalized around the ring structure.

Correct answer: Both (a) and (b)
  • A. Isomerization
  • B. Aromatization
  • C. Dealkylation
  • D. Rearrangement

Explanation: Aromatization is a chemical reaction in which an aromatic system is formed from a single nonaromatic precursor.

Correct answer: Aromatization
  • A. A
  • B. B
  • C. C
  • D. D

Explanation: The benzyl free radical has the formula C 6H 5CH 2•. The benzyl cation or phenylcarbenium ion is the carbocation with formula C 6H 5CH+2…

Correct answer: C
  • A. dil. NaOH
  • B. dil. HNO3
  • C. Conc. HNO3
  • D. Acidified KMnO4

Explanation: Toluene should be heated in presence of acidified \[KMn{O_4}\] to carry out oxidation of Toluene.

Correct answer: Acidified KMnO4
  • A. Dewar
  • B. Faraday
  • C. Down
  • D. Kekule

Explanation: German chemist August Kekulé visualized the ring structure of benzene in 1865.

Correct answer: Kekule
  • A. Three double bonds
  • B. Two double bonds
  • C. One double bond
  • D. Delocalized π-electron charge

Explanation: Benzene is an organic chemical compound with the molecular formula C6H6.

Correct answer: Delocalized π-electron charge
  • A. Normal series of paraffins
  • B. Alkene
  • C. Benzene
  • D. Cyclohexane

Explanation: In the International Union of Pure and Applied Chemistry (IUPAC) system, aromatic hydrocarbons such as those above are named as…

Correct answer: Benzene
  • A. AlCl3
  • B. HNO3
  • C. BeCl2
  • D. NaCl

Explanation: Aluminium trichloride (AlCl3) is often used as a catalyst in Friedel-Crafts reactions since it acts as a Lewis acid and coordinates with…

Correct answer: AlCl3
  • A. Substitution reactions
  • B. Addition reactions
  • C. Oxidation reactions
  • D. Elimination reactions

Explanation: Due to presence of pi-bonds benzene can not under go elimination reaction.

Correct answer: Elimination reactions
  • A. Toluene
  • B. Benzene
  • C. Nitrobenzene
  • D. Chlorobenzene

Explanation: A process for the sulphonation of toluene in the liquid phase to produce a product comprising chiefly p-toluene sulphonic acid which…

Correct answer: Toluene
  • A. Benzene
  • B. Ethene
  • C. Ethane
  • D. Ethyne

Explanation: The π bond in ethene is weak compared to the sigma bond between the two carbons.

Correct answer: Ethene
  • A. They have high percentage of hydrogen
  • B. They have a ring structure
  • C. They have high percentage of carbon
  • D. They resist reaction with air

Explanation: The aromatic compound displays aromaticity. They burn with a strong sooty yellow flame.

Correct answer: They have high percentage of carbon
  • A. Isomerization
  • B. Aromatization
  • C. Dealkylation
  • D. Rearrangement

Explanation: Aromatization is a chemical reaction in which an aromatic system is formed from a single nonaromatic precursor.

Correct answer: Aromatization
  • A. -NH2
  • B. -OCH3
  • C. -SO3H
  • D. -OH

Explanation: -SO3H is correct because the sulfonic acid group is meta-directing in electrophilic substitution reactions of monosubstituted benzene due…

Correct answer: -SO3H
  • A. Toluene
  • B. Xylene
  • C. Benzoic acid.
  • D. Acetophenone

Explanation: The introduction of an alkyl group in the benzene ring in the presence of an alkyl halide and a catalyst AICI3 is called Friedel-Crafts…

Correct answer: Benzoic acid.