Asked in FBISE Chemistry 2022 — Paper 1 2022Moderate

Which of the following is meta directing group in the electrophilic substitution reactions of monosubstituted benzene?

Correct answer: C. -SO3H

  • A. -NH2
  • B. -OCH3
  • C. -SO3H
  • D. -OH

Explanation

-SO3H is correct because the sulfonic acid group is meta-directing in electrophilic substitution reactions of monosubstituted benzene due to its strong electron-withdrawing effect.

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About Benzene and Aromatic Compounds

Benzene has a planar ring of delocalised π electrons, giving aromatic stability and equal carbon-carbon bond lengths. The topic covers resonance, electrophilic substitution reactions such as nitration, halogenation, sulphonation and Friedel-Crafts reactions, along with substituent effects and the distinction between substitution in benzene and addition in ordinary alkenes.

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