All Free Chemistry MCQs with Answers

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13,720 questions · page 542 of 686

  • A. -6
  • B. +3
  • C. -3
  • D. +6

Explanation: The algebraic sum of oxidation no. of all atoms in a complex ion is equal to the charge on that ion,i.e., a + 6 × (-1) = - 3. a = + 3.

Correct answer: +3
  • A. FeSO4
  • B. KCl.MgCl26H2O
  • C. Al2(CO3)3
  • D. NH4Br.

Explanation: A simple salt is a compound which has been prepared by the combination of two simple ions like Na+ and Cl- ions to form NaCl.

Correct answer: KCl.MgCl26H2O
  • A. Solution of iron salt does not give blue colour with indicator.
  • B. Solution of iron salt gives blue colour with indicator.
  • C. No colour before and after with indicator.
  • D. Always blue colour before and after

Explanation: At the end point, there is no Fe2+. All iron in Fe3+ hence no blue colour with K3[Fe(CN)6] hence (A).

Correct answer: Solution of iron salt does not give blue colour with indicator.
  • A. +1.
  • B. +3.
  • C. -1.
  • D. -3.

Explanation: We know that CO is a neutral ligand and K carries a charge of +1. Therefore, the complex can be written as K+ [Co(CO)4]-.

Correct answer: -1.
  • A. a central metal ion with d8 configuration has two unpaired electrons.
  • B. an ion with d6 configuration is diamagnetic in a strong field.
  • C. an ion with d5 configuration has one unpaired electron both in weak and strong fields.
  • D. in d4, d5, d6 and d7 configurations, weak and strong field complexes have different numbers of unpaired electrons.

Explanation: This statement is fundamentally incorrect because the number of unpaired electrons changes:Weak field: All five electrons are unpaired…

Correct answer: an ion with d5 configuration has one unpaired electron both in weak and strong fields.
  • A. Geometrical isomers.
  • B. Linkage isomers
  • C. Ligand isomers.
  • D. Ionisation isomers.

Explanation: The ligand NO2 has two types of linkage with the central atom. In NO2, N donates an electron pair, while in O NO the O atom donates the…

Correct answer: Linkage isomers
  • A. [Pt(NH3)Cl3]Br2 and [Pt(NH3)4Br2]Cl2
  • B. [Co(NH3)5NO3]SO4 and [Co(NH3)5SO4]NO3
  • C. [Cr(H2O)5SCN]2+ and [Cr(H2O)5NCS]2+
  • D. [Cr(H2O)6]Cl3 and [Cr(H2O)5Cl2]Cl2.H2O

Explanation: [Cr(H2O)5SCN]2+ and [Cr(H2O)5NCS]2+ exhibits linkage isomerism.

Correct answer: [Cr(H2O)5SCN]2+ and [Cr(H2O)5NCS]2+
  • A. 1
  • B. 2
  • C. 4
  • D. 5

Explanation: Hexafluoroferrate (III) is [FeF6]3-. The O.N. of Fe in it is x + (-6) = - 3 or x - 6 = -3 or x = + 3.Thus in it, Fe is present as Fe3+…

Correct answer: 5
  • A. 1
  • B. 2
  • C. 5
  • D. 3

Explanation: The configuration of Mn is [Ar]d5. Thus it is expected to have 5 unpaired electrons.

Correct answer: 1
  • A. CrCl3.6H2O
  • B. [Cr(H2O)3Cl3].(H2O)3
  • C. [CrCl2(H2O)4]Cl.2H2O
  • D. [CrCl(H2O)5]Cl2.H2O

Explanation: [CrCl2(H2O)4]Cl.2H2O has only one ionisable Cl out of three Cl atoms present in the compound.

Correct answer: [CrCl2(H2O)4]Cl.2H2O
  • A. 0
  • B. +1
  • C. +2
  • D. +1.5

Explanation: Ag in Tollens reagent exists as Ag2O2 × a + 1 × (-2) = 0a = + 1.

Correct answer: +1
  • A. d3, d5, d6, d9
  • B. d4, d5, d6, d7
  • C. d2, d5, d7, d9
  • D. d4, d6, d7, d10

Explanation: Metal ions with d4, d5, d6 and d7 configuration can form high spin and low spin complexes.

Correct answer: d4, d5, d6, d7
  • A. [Ar](n-1)d1-10ns1-2
  • B. [Ar](n-1)d1-10ns2
  • C. [Ar](n-1)d1-2ns1-2
  • D. [Ar](n-2)d1-2ns1-2

Explanation: d-block (outer) transition elements are those in which d-subshell of penultimate shell (inner to valence shell) is in process of…

Correct answer: [Ar](n-1)d1-10ns1-2
  • A. [Ar] 3d34s2
  • B. [Ar] 3d44s2
  • C. [Ar] 3d4s2
  • D. [Ar] 3d54s2

Explanation: Electronic configuration of Mn is 25Mn 18[Ar] 4s23d5.

Correct answer: [Ar] 3d54s2
  • A. Sc
  • B. Mn
  • C. Ti
  • D. Zn

Explanation: (A) 21Sc 18[Ar] 4s2 3d1Sc+3 18[Ar] 4sº 3dº (B) 21Ti 18[Ar] 4s2 3d2Ti+3 18[Ar] 4sº 3d1 (C) 25Mn 18[Ar] 4s2 3d5Mn+2 18[Ar] 4sº 3d5 (D) 30Zn…

Correct answer: Zn
  • A. V
  • B. Ti
  • C. Sc
  • D. Cr

Explanation: 21Sc =18[Ar] 4s2 3d121Sc+3 = 18[Ar] 4s° 3d°Scandium in +3 state has same electronic configuration as 18Ar.Ar = 1s22s22p63s23p6

Correct answer: Sc
  • A. 0
  • B. +2
  • C. +1
  • D. +3

Explanation: Cu+118[Ar] 4s° 3d10Zn+2 18[Ar] 4s° 3d10 As per the electronic configuration, Cu in +1 oxidation state, achieves electronic configuration…

Correct answer: +1
  • A. Its d-subshell is incomplete.
  • B. Its d-subshell is complete
  • C. It is relatively soft metal
  • D. It has two electrons in outermost shell

Explanation: 30Zn 18[Ar] 4s2 3d10 Zn+2 18[Ar] 4s° 3d10 Zinc (Zn) has a completely filled d-subshell (3d10) in its electronic configuration.

Correct answer: Its d-subshell is complete
  • A. +7
  • B. -7
  • C. +6
  • D. +4

Explanation: Mn belongs to group (VIIB)of periodic table. So, its maximum oxidation state should be +7.

Correct answer: +7