A coordination complex compound of cobalt has a molecular formula containing five ammonia molecules, one nitro group, and two chlorine atoms for one cobalt atom. One mole of this compound produces three-mole ions in an aqueous solution. By the reaction of this solution with excess silver nitrate solution, two molecules of AgCl get precipitated. The ionic formula of this compound would be:

Correct answer: C. [Co(NH3)5NO2]Cl2

  • A. [Co(NH3)4NO2Cl] [(NH3)Cl]
  • B. [Co(NH3)5Cl] [Cl(NO2)]
  • C. [Co(NH3)5NO2]Cl2
  • D. [Co(NH3)5] [(NO2)2Cl2]

Explanation

Because only (C) gives two moles of AgCl with AgNO3 and yields three ions (including two ionizable Cl- ions) in an aqueous solution.[Co(NH3)5NO2]Cl2] [Co(NH3)5NO2]2+ + 2Cl-

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About Transition Elements

Transition elements are identified by their partially filled d subshells in atoms or common ions. The topic covers the electronic structure of d-block elements, including the filling order of 4s and 3d orbitals, variable oxidation states and the distinction between transition elements and elements with completely filled d subshells.

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