Free Aldehydes and Ketones MCQs with Answers

679 Aldehydes and Ketones MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Aldehydes and ketones contain the polar carbonyl group, but aldehydes are generally more readily oxidised and more reactive than ketones. Coverage includes preparation by oxidation or reduction routes, nucleophilic addition of reagents such as hydrogen cyanide and bisulfite, and tests that distinguish aldehydes from ketones.

Last updated

Read the Aldehydes and Ketones notesFree MDCAT chapter notes with key terms

679 questions · page 19 of 34

  • A. 2-propanol
  • B. I-Butonal
  • C. 2-Butanol
  • D. Teritary butyl alcohol

Explanation: Methyl ethyl ketone is a 4-C ketone. So, it requires a 4-C secondary alcohols

Correct answer: 2-Butanol
  • A. Reduction
  • B. Substitution
  • C. Oxidation
  • D. Elimination

Explanation: This reaction is involving oxidation of ethanol.

Correct answer: Oxidation
  • A. - CH3 is oxidized to CH2-OH
  • B. - OH is oxidized to-CO group
  • C. >CH2 is oxidized to -CHO group
  • D. -CH2OH is oxidized to -CHO

Explanation: Explanation is given as: During the oxidation of ethanol to ethanal, the carbon atom (CH2) adjacent to the hydroxyl group (OH) in ethanol…

Correct answer: >CH2 is oxidized to -CHO group
  • A. Aldehydes
  • B. Ketones
  • C. Pure alcohols only
  • D. Both A and B.

Explanation: The aldehydes and ketones give yellow or orange colour crystals (2,4-dinitrophenylhydrozone)

Correct answer: Both A and B.
  • A. Formaldehyde cyanohydrin
  • B. Acetaldehyde cyanohydrin
  • C. Acetone cyanohydrins
  • D. Butanone cyanohydrin

Explanation: When HCN is added to any carbonyl compound it produces an adduct which contain both-CN group and -OH group attached to one carbon, called…

Correct answer: Acetaldehyde cyanohydrin
  • A. CH3CH2CH2CH2COCH3
  • B. CH3CH = CHCH2CH(OH)CH3
  • C. CH3CH2CH2CH2CH(OH)CH3
  • D. All of these

Explanation: NaBH4 can reduce > C=O group to > CH-OH group but cannot reduce > C=C;. So, in product >C = C< will remain intact.

Correct answer: CH3CH = CHCH2CH(OH)CH3
  • A. Formaldehyde
  • B. Propanone
  • C. Acetaldehyde
  • D. All of these

Explanation: Reactivity order: Aldehyde> Ketone Small aldehyde>large aldehyde Small ketone>large ketone Unsymetrical ketone>symmetrical ketone…

Correct answer: Formaldehyde
  • A. H
  • B. H-
  • C. H+
  • D. H2

Explanation: H-: This represents a hydride ion (H⁻), which is the active reducing species in sodium borohydride (NaBH₄).

Correct answer: H-
  • A. Methyl alcohol
  • B. Isopropyl alcohol
  • C. Ethyl alcohol
  • D. Neopentyl alcohol

Explanation: Acetone is a 3-C ketone. On reduction, it will produce a 3-C secondary alcohol.

Correct answer: Isopropyl alcohol
  • A. HCHO and CH3CHO
  • B. CH3COCH3 and CH3COCH2CH3
  • C. CH3CHO and CH3COCH3
  • D. CH3COOH and CH3COCH3

Explanation: All the aliphatic aldehydes gives positive test (silver minor formation on the inner side of test tube) while ketones don't.

Correct answer: CH3CHO and CH3COCH3
  • A. CH3CH2CHO
  • B. HCHO
  • C. CH3CHO
  • D. CH3COCH3

Explanation: Ketones are reluctant towards oxidation. Acetone is a ketone. Ketones are generally less susceptible to oxidation compared to aldehydes.

Correct answer: CH3COCH3
  • A. CuSO4 + NaOH + Citric acid
  • B. AgNO3 + NH4OH
  • C. CuSO4 + NaOH + Tartaric acid
  • D. K2Cr2O7 + Conc. H2SO4

Explanation: A, B, C are weak oxidizing agent, so they can oxidize aldehydes only (due to high reactivity than ketone) but not ketones but the…

Correct answer: K2Cr2O7 + Conc. H2SO4
  • A. Ag
  • B. Cuprix oxide
  • C. Cuprous oxide
  • D. Soduim carboxylate

Explanation: Fehling's solution is alkaline solution containing cupric tartarate ion.

Correct answer: Cuprous oxide
  • A. HCHO
  • B. -CHO
  • C. CH3CHO
  • D. CH3COCH3

Explanation: Aliphatic aldehydes are reactive than aromatic aldehydes and ketones so, a small aliphatic aldehyde can reduce Tollen's reagent

Correct answer: HCHO
  • A. Acetophenone
  • B. Benzaldehyde
  • C. 2-Butcne, 2of
  • D. 3-Methyl 2-pentanone

Explanation: 3-Methyl-2-pentartone gives 3-Methyl-2-pentanol on reduction with NaBH4'

Correct answer: 3-Methyl 2-pentanone
  • A. Sodium acetate
  • B. Ammonium acetate
  • C. No salt formed
  • D. Silver chloride

Explanation: Ammonium acetate. Explanation: Ammonical silver nitrate is a reagent used to test for the presence of halides.

Correct answer: Ammonium acetate
  • A. HCHO
  • B. CH3CHO
  • C. CH3-CH2-CHO
  • D. CH3CH2 -OH

Explanation: Aldehydes and small methyl ketones react with a saturated aqueous solution of sodium bisulphite to form a crystalline white precipitate of…

Correct answer: CH3CH2 -OH
  • A. α-C
  • B. α-H
  • C. Basic medium
  • D. All of these

Explanation: Aldehydes and ketones possessing ɑ-hydrogen atoms react with a cold dilute solution of an alkali to form addition products known as aldols.

Correct answer: All of these
  • A. Methanol
  • B. Ethanol
  • C. Propanone
  • D. 2-pentanone

Explanation: Aldehydes and ketones possessing α-hydrogen atoms react with a cold dilute solution of an alkali to form addition products known as…

Correct answer: Methanol
  • A. NaHSO3
  • B. HCN
  • C. NH2NH2
  • D. Aldol

Explanation: This reaction is used for the separation and purification of carbonyl compounds from non-carbonyl compounds such as alcohols.

Correct answer: NaHSO3