All Free Chemical Engineering MCQs with Answers

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6,983 questions · page 183 of 350

  • A. V
  • B. V/n
  • C. V.n
  • D. 1/V

Explanation: PFR volumes in series add, and a series of ideal plug-flow sections behaves like one ideal PFR having the same total volume.

Correct answer: V
  • A. Linearly with time
  • B. Exponentially with time
  • C. Very abruptly towards the end of the reaction
  • D. Logarithmically with time

Explanation: Integrating the first-order rate law gives C_A = C_A0e⁻ᵏᵗ, so concentration falls exponentially rather than linearly with time.

Correct answer: Exponentially with time
  • A. None of the above
  • B. Reaction
  • C. External mass transfer
  • D. Diffusion within the pellet

Explanation: A much lower concentration at the pellet centre than at its surface indicates a steep internal concentration gradient.

Correct answer: Diffusion within the pellet
  • A. Ideal tubular-flow reactor
  • B. Batch reactor
  • C. Slurry reactor
  • D. CSTR

Explanation: Space time is based on reactor volume and inlet volumetric flow, making it convenient for sizing an ideal tubular-flow reactor.

Correct answer: Ideal tubular-flow reactor
  • A. Ideal plug flow
  • B. Dead zone
  • C. Bypass
  • D. Channelling

Explanation: A long tail means some material remains in the packed bed much longer than the main flow, which indicates stagnant or dead regions.

Correct answer: Dead zone
  • A. Inversely proportional to
  • B. Independent of
  • C. Proportional to
  • D. Proportional to the square of

Explanation: Without a chain mechanism, doubling the amount of catalyst doubles the available active surface and hence the overall rate, provided…

Correct answer: Proportional to
  • A. Decreases
  • B. Remains unchanged
  • C. Increases
  • D. Unpredictable from the data

Explanation: For an exothermic reversible reaction, increasing temperature shifts equilibrium toward the reactants, so the equilibrium conversion…

Correct answer: Decreases
  • A. CSTR of volume V
  • B. PFR of volume V
  • C. CSTR of volume V/X
  • D. PFR of volume V/X

Explanation: Ideal PFRs in series behave as one continuous PFR because each element experiences the same plug-flow progression.

Correct answer: PFR of volume V
  • A. Equilibrium constant is infinite
  • B. Fractional conversion of 'A' at equilibrium is unity
  • C. All A., B. and C.
  • D. Concentration of 'A' at equilibrium is zero

Explanation: An irreversible reaction is the limiting reversible case with an infinite equilibrium constant.

Correct answer: All A., B. and C.
  • A. 18
  • B. 24
  • C. 6
  • D. 12

Explanation: A 75% conversion leaves 25% of A, or one-fourth of its initial amount. For a first-order reaction this requires two half-lives, so the…

Correct answer: 24
  • A. 0.5
  • B. -0.5
  • C. 1
  • D. 1.5

Explanation: For 2A → R, the change in total gas moles is 1 − 2 = −1 for every 2 moles of A consumed.

Correct answer: -0.5
  • A. Rate constant
  • B. Frequency factor
  • C. Rate of reaction
  • D. Activation energy

Explanation: The Arrhenius relation, k = A exp(−Ea/RT), describes how the rate constant changes with temperature.

Correct answer: Rate constant
  • A. CSTR
  • B. CSTR in series
  • C. Recycle reactor
  • D. Plug flow reactor

Explanation: A recycle reactor returns product to the feed, which is especially useful when the product catalyses the reaction because it supplies…

Correct answer: Recycle reactor
  • A. Higher
  • B. Much higher
  • C. Lower
  • D. Much lower

Explanation: Cold-shot cooling removes heat by injecting a colder feed directly into the reacting mixture.

Correct answer: Much lower
  • A. Temperature of the system
  • B. Time of reaction
  • C. Extent of reaction
  • D. Initial concentration of the reactants

Explanation: The Arrhenius relation, k=A exp(-E/RT), shows that the rate constant is primarily dependent on temperature for a given reaction.

Correct answer: Temperature of the system
  • A. 500
  • B. 0
  • C. 750
  • D. ∞

Explanation: The dispersion number compares axial mixing with convective transport. Ideal plug flow has no axial dispersion, so D/(uL) approaches zero.

Correct answer: 0
  • A. Itself has very high activity
  • B. Acts as a catalyst support
  • C. Improves the activity of a catalyst
  • D. All A., B. and C.

Explanation: A promoter is an additive that improves a catalyst's activity, selectivity, or stability, although it may have little catalytic activity…

Correct answer: Improves the activity of a catalyst
  • A. 1/(time)n
  • B. (Concentration)1 - n/(time)
  • C. (Concentration)n - 1/(time)
  • D. None of these

Explanation: For an nth-order rate law, rate=kC^n, the units of k must make the result concentration per time.

Correct answer: (Concentration)1 - n/(time)
  • A. Extent of non-ideal flow in the vessel
  • B. Reaction mechanism
  • C. Activation energies of a reaction
  • D. None of these

Explanation: The exit age distribution, or residence-time distribution, shows how long fluid elements remain in the vessel.

Correct answer: Extent of non-ideal flow in the vessel