Moderate

Which of the following factor(s) affect a reversible chemical reaction in accordance with the Le - Chatelier Principle?

Correct answer: D. Pressure, concentration and temperature

  • A. Pressure
  • B. Temperature
  • C. Concentration
  • D. Pressure, concentration and temperature

Explanation

The Le Chatelier's principle states that when a system in equilibrium is subjected to a change in conditions, the system will adjust itself in a way that minimizes the effect of that change. In the context of reversible chemical reactions, several factors can influence the equilibrium position, and hence the direction in which the reaction will proceed. Here are some factors and how they affect reversible chemical reactions according to Le Chatelier's principle:1. Concentration: If the concentration of a reactant or product is changed, the system will shift to minimize the effect of that change. An increase in the concentration of a reactant will cause the reaction to shift in the forward direction to consume the excess reactant. Conversely, an increase in the concentration of a product will drive the reaction in the reverse direction to consume the excess product.2. Pressure: For gaseous reactions, changes in pressure can affect the equilibrium position. According to Le Chatelier's principle, an increase in pressure will shift the equilibrium towards the side with fewer moles of gas to reduce the pressure. Conversely, a decrease in pressure will shift the equilibrium towards the side with more moles of gas.3. Temperature: Altering the temperature can have a significant impact on reversible reactions. In an exothermic reaction (heat-releasing), increasing the temperature will favor the reverse reaction as it consumes heat. In contrast, decreasing the temperature will favor the forward reaction. For an endothermic reaction (heat-absorbing), the opposite holds true.4. Catalysts: Catalysts increase the rate of a chemical reaction by providing an alternative reaction pathway with lower activation energy. They do not affect the equilibrium position or the composition of the equilibrium mixture. However, by speeding up the attainment of equilibrium, they can influence the time it takes to reach equilibrium.5. Inert gases: Inert gases do not participate in the reaction. Their introduction at constant volume does not affect the equilibrium position. However, if the reaction involves gases, increasing the total pressure by introducing an inert gas will cause no effect on the equilibrium composition.These factors demonstrate how changes in concentration, pressure, temperature, and the presence of catalysts or inert gases can influence the direction in which a reversible chemical reaction proceeds according to Le Chatelier's principle.Le-Chatelier studied the effects of temperature, pressure and concentration on equilibria and explained the Le-Chatelier's principle which states that: If stress is applied on any system at equilibrium, the system acts in a way to nullify, to the farthest extent, the effect of that stress. This stress may be in the form of a change in pressure, temperature or concentration. Increase in pressure shifts the equilibrium towards the side which has fewer moles. Increase in temperature shifts the equilibrium towards the product side for endothermic reactions and towards the reactants side for endothermic reactions. Increase in concentration of reactants shifts the equilibrium towards the product side while increase in products shifts it towards reactant side. Therefore, option D is correct as it includes all of these factors.

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About Chemical Equilibrium

Reversible reactions reach dynamic equilibrium when forward and reverse rates become equal, and Le Chatelier's principle predicts the effect of changing concentration, pressure or temperature. The chapter also covers solubility product, the common ion effect, buffer action and the conditions used in Haber's process, with equilibrium shifts distinguished from changes in the equilibrium constant.

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