Asked in Premeth Test 11 — S and P Block, D Block and Chemical Bonding (13 March 2025) 2025Moderate

Which of the following cations of alkali metals has least heat of hydration?

Correct answer: D. Cs+

  • A. Li+
  • B. Na+
  • C. K+
  • D. Cs+

Explanation

When considering the heat of hydration, the size and charge density of cations play a crucial role. In this case, Cesium ion (Cs+) stands out as it is the largest among alkali metal ions with the lowest charge density. This weak attraction to water molecules leads to the least heat of hydration. Therefore, option D is correct.Options A, B, and C are incorrect as they each have smaller sizes or higher charge densities compared to Cesium ion, resulting in higher heat of hydration values.

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About Reactions of Group I Elements

Group I elements have one valence electron, so their reactivity increases down the group as ionisation energy decreases. Their reactions with water, oxygen, hydrogen and halogens produce hydroxides, oxides, hydrides and halides, while the behaviour of lithium differs from the heavier metals because of its small ionic size.

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