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Which of the following actions does NOT affect the equilibrium of a reaction?

Correct answer: B. Adding/removing a catalyst

  • A. Adding/subtracting heat
  • B. Adding/removing a catalyst
  • C. Increasing/decreasing concentration of reactants
  • D. Increasing/decreasing volume of reactants

Explanation

The equilibrium of a reaction can be changed by several factors. If you recall Le Châtelier's principle, you can rule out any answer choice that would shift the direction of an equilibrium. Adding or subtracting heat would shift the equilibrium based on the enthalpy change of the reaction. Adding reactant concentration would shift the equilibrium in the direction of the product, and the opposite would occur if concentrations were decreased. Changing the volume of a reactant would change its concentration, so that would have the same effect. Only (B), adding or removing a catalyst, would change the reaction rate without changing where the equilibrium lies.

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About Chemical Equilibrium

Reversible reactions reach dynamic equilibrium when forward and reverse rates become equal, and Le Chatelier's principle predicts the effect of changing concentration, pressure or temperature. The chapter also covers solubility product, the common ion effect, buffer action and the conditions used in Haber's process, with equilibrium shifts distinguished from changes in the equilibrium constant.

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