The value of the rate constant k for a given reaction changes when

  • A. the concentration of the reactants is increased
  • B. the volume of the vessel is changed
  • C. the temperature is changed
  • D. more product is removed

Explanation

The rate constant is constant only at a fixed temperature; the Arrhenius equation shows it rising sharply as temperature increases or as activation energy falls, which is also why a catalyst increases k. Changing concentration changes the rate but leaves k untouched, since the concentration term is already written separately in the rate equation. This distinction between rate and rate constant is examined frequently.

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