The half life of a first order reaction

Correct answer: C. is constant and independent of the initial concentration

  • A. doubles as the reaction proceeds
  • B. depends on the initial concentration
  • C. is constant and independent of the initial concentration
  • D. is always one second

Explanation

For first order kinetics the time taken for the concentration to fall by half is fixed, so successive halvings take equal times, and this is precisely why radioactive decay is described by a half life. The relationship is half life equals 0.693 divided by k. For zero and second order reactions the half life does depend on the starting concentration.

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About Rate Constant

The rate constant, k, connects reaction rate with reactant concentrations in a rate law and has a value fixed for a particular reaction at a given temperature. Questions involve determining k from rate data, identifying its units for different reaction orders, and applying the Arrhenius equation to temperature changes.

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