Free Rate Constant MCQs with Answers

16 Rate Constant MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

The rate constant, k, connects reaction rate with reactant concentrations in a rate law and has a value fixed for a particular reaction at a given temperature. Questions involve determining k from rate data, identifying its units for different reaction orders, and applying the Arrhenius equation to temperature changes.

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16 questions

  • A. mol dm-3 s-1
  • B. s-1
  • C. mol-1 dm3 s-1
  • D. mol-2 dm6 s-1

Explanation: For a first order reaction rate equals k times concentration, so k must have units of rate divided by concentration, which reduces to…

Correct answer: s-1
  • A. the concentration of the reactants is increased
  • B. the volume of the vessel is changed
  • C. the temperature is changed
  • D. more product is removed

Explanation: The rate constant is constant only at a fixed temperature; the Arrhenius equation shows it rising sharply as temperature increases or as…

Correct answer: the temperature is changed
  • A. doubles as the reaction proceeds
  • B. depends on the initial concentration
  • C. is constant and independent of the initial concentration
  • D. is always one second

Explanation: For first order kinetics the time taken for the concentration to fall by half is fixed, so successive halvings take equal times, and this…

Correct answer: is constant and independent of the initial concentration
  • A. the activation energy increases
  • B. the temperature falls
  • C. the activation energy decreases or the temperature rises
  • D. the concentration of reactants rises

Explanation: The equation contains an exponential term in which activation energy appears with a negative sign and temperature in the denominator, so…

Correct answer: the activation energy decreases or the temperature rises
Fairly easy
  • A. Rate law
  • B. Rate constant
  • C. Reaction rate
  • D. Reaction order

Explanation: The rate law, or rate equation, states the rate as the rate constant multiplied by concentration terms raised to their experimentally…

Correct answer: Rate law
  • A. All electrolytes
  • B. Strong electrolytes
  • C. Non electrolytes
  • D. Weak electrolytes

Explanation: Ostwald's dilution law relates the degree of ionisation of a weak electrolyte to its concentration and is derived using its equilibrium…

Correct answer: Weak electrolytes
  • A. Arrhenius constant
  • B. Molecularity
  • C. Specific rate constant
  • D. Ideal rate constant

Explanation: The specific rate constant, or rate constant k, is the reaction rate when the molar concentrations of all reactants in the rate expression…

Correct answer: Specific rate constant
  • A. I and II quadrant
  • B. II and III quadrant
  • C. III and IV quadrant
  • D. II and IV quadrant

Explanation: The Arrhenius equation in logarithmic form is log k = log A - Ea/(2.303R) x 1/T, so a plot of log k against 1/T has a negative slope.

Correct answer: II and IV quadrant
  • A. Time
  • B. Concentration of the reactant
  • C. Temperature
  • D. Concentration of the product

Explanation: For a given reaction, the first-order rate constant remains independent of reactant concentration and changes mainly with temperature…

Correct answer: Temperature
  • A. s-1
  • B. mol dm-3 s-1
  • C. mol-1 dm3 s-1
  • D. mol-2 dm6 s-1

Explanation: For a zero-order reaction, rate = k, so k has the same dimensions as rate: concentration per time. Therefore its unit is mol dm^-3 s^-1.

Correct answer: mol dm-3 s-1
  • A. First order reaction
  • B. Second order reaction
  • C. Zero order reaction
  • D. Third order reaction

Explanation: For a zero-order reaction, rate = k, so the numerical value and units of k are the same as those of the reaction rate, commonly mol dm-3…

Correct answer: Zero order reaction
  • A. conc.s-1
  • B. M2s-1
  • C. s-1
  • D. M-1s-1
  • E. M-1s-2

Explanation: The unit of the rate constant for a first-order reaction is s-1. This is because, for a first-order reaction, the rate is directly…

Correct answer: s-1
  • A. First order reaction
  • B. Zero order reaction
  • C. Second order reaction
  • D. Third order reaction

Explanation: Rate law general form:Rate = k[A]n n = order of reactionk = rate constantUnit of k depends on the order:k = Rate[A]n

Correct answer: Zero order reaction
  • A. Has fixed value at fixed temperature
  • B. Changes with change in temperature
  • C. Does not depend upon concentration of reactants
  • D. None of the above

Explanation: The explanation for this question will be added soon.

Correct answer: None of the above
  • A. Unit rate constant
  • B. Specific rate constant
  • C. Relative rate constant
  • D. Average rate constant

Explanation: A specific rate constant at a given temperature may be defined as the rate of reaction when the molar concentration of each reactant is…

Correct answer: Specific rate constant
  • A. Sec
  • B. Sec-¹
  • C. Mol dm-³sec-¹
  • D. None of the above

Explanation: Because the units of the reaction rate are always moles per liter per second, the units of a first-order rate constant are reciprocal…

Correct answer: Sec-¹

Rate Constant MCQs: common questions

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There are 16 Rate Constant MCQs in the Chemistry bank, shown 20 to a page with the correct answer and an explanation on each.

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