Asked in Premeth Test 19 — Solids

Sodium (Na = 23) crystallizes in a bcc arrangement with the interfacial separation between the atoms at the edge 53.6pm. The density of sodium crystal is:

Correct answer: D. None of these

  • A. 2.07 g/cc
  • B. 2.46 g/cc
  • C. 1.19 g/cc
  • D. None of these

Explanation

Sodium (Na) has a body-centered cubic (BCC) structure.Given interatomic distance = 53.6 pm, this is not the unit cell edge length.In BCC, edge length a=2×distance/sqr3 so a is about 62 pm.Calculate density using formula:density=mass of atoms in unit cell / volume of unit cellThis calculation gives a density much less than the options provided.Real sodium density is about 0.97 g/cm³, less than all given options.So, the correct choice is "None of these" because none match the expected or calculated density.

Written and checked by , M.Phil ChemistryLast updated
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Solids are classified by particle arrangement and bonding into crystalline, ionic and molecular forms. Questions cover crystal lattices, the shapes and properties of ionic crystals, and lattice energy, including how ion charge and ionic size affect the strength of attractions within an ionic solid.

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