Asked in PMC Practice Test 8 (2021) 2021Moderate

During the reduction of aldehydes with NaBH4, which of the following intermediate is formed?

Correct answer: D. Alkoxide ion

  • A. Carbanion
  • B. Carbocation
  • C. Carbene
  • D. Alkoxide ion

Explanation

During the reduction of aldehydes with NaBH4, the "alkoxide ion" is seen as the intermediate formed hence the answer is D.

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About Nucleophilic Addition Reactions

Nucleophilic addition occurs at the polar carbonyl group of aldehydes and ketones, where a nucleophile attacks the electron-deficient carbon atom. Reactions with hydrogen cyanide, sodium bisulfite, alcohols and Grignard reagents are explained through tetrahedral intermediates, acid or base catalysis, and the different reactivity of aldehydes and ketones.

Practise Aldehydes and Ketones

679 free Aldehydes and Ketones MCQs from Chemistry, each with the correct answer and an explanation. Unlimited attempts, no account needed.

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