Asked in NUMS 2019 (cancelled sitting) 2019Moderate

By treating CO2 with Grignard's reagent, the following compound is obtained;

Correct answer: C. Carboxylic acid

  • A. Aromatic compounds
  • B. Alcohols
  • C. Carboxylic acid
  • D. Ethers

Explanation

When carbon dioxide (CO₂) reacts with a Grignard reagent (RMgX), a carboxylic acid is formed. The Grignard reagent acts as a nucleophile, attacking the electrophilic carbon in CO₂. After the addition of the Grignard reagent, the intermediate is hydrolyzed, resulting in the formation of a carboxylic acid and a magnesium salt.

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About Nomenclature, Structure and Preparation

Carboxylic acids are prepared by oxidising primary alcohols or aldehydes, hydrolysing nitriles, esters and amides, and carbonating suitable organometallic compounds. Their structures, IUPAC naming, resonance stabilisation and acidic character explain why carboxylic acids differ from alcohols and phenols, despite all containing oxygen and hydrogen.

Practise Carboxylic Acids

550 free Carboxylic Acids MCQs from Chemistry, each with the correct answer and an explanation. Unlimited attempts, no account needed.

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