Free Reactivity of Carboxylic Acids MCQs with Answers

56 Reactivity of Carboxylic Acids MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Carboxylic acids show acidic behaviour because their carboxylate ions are resonance-stabilised, and electron-withdrawing groups can change their strength. Reactions include neutralisation, esterification, formation of acid chlorides and amides, reduction, decarboxylation and substitution at the acyl carbon, which differs from the reactions of phenols.

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  • A. they contain more hydrogen atoms
  • B. the carboxylate ion formed is stabilised by delocalisation of the negative charge over two oxygen atoms
  • C. they are liquids at room temperature
  • D. their molecules are larger

Explanation: Losing the acidic hydrogen gives an ion whose charge is shared equally between the two oxygens, so the two carbon to oxygen bonds become…

Correct answer: the carboxylate ion formed is stabilised by delocalisation of the negative charge over two oxygen atoms
Hard
  • A. sodium ethanoate, water and carbon dioxide
  • B. sodium ethanoate and hydrogen
  • C. ethanol and carbon dioxide
  • D. no reaction

Explanation: Being a stronger acid than carbonic acid, ethanoic acid displaces carbon dioxide from a carbonate, and the effervescence produced is the…

Correct answer: sodium ethanoate, water and carbon dioxide
  • A. donates electrons to the carboxyl group
  • B. increases the molar mass
  • C. withdraws electron density, spreading and stabilising the negative charge of the anion
  • D. makes the molecule non polar

Explanation: The electron withdrawing inductive effect of chlorine pulls charge away from the carboxylate oxygens, so the ion is more stable and the…

Correct answer: withdraws electron density, spreading and stabilising the negative charge of the anion
  • A. are ionised
  • B. form dimers held together by two hydrogen bonds
  • C. form covalent bonds with one another
  • D. are non polar

Explanation: Two molecules pair up so that the hydroxyl hydrogen of each bonds to the carbonyl oxygen of the other, giving a cyclic dimer with double…

Correct answer: form dimers held together by two hydrogen bonds
  • A. an aldehyde only
  • B. a primary alcohol
  • C. a ketone
  • D. an alkane

Explanation: Lithium aluminium hydride is powerful enough to reduce the carboxyl group all the way to a primary alcohol, passing through the aldehyde…

Correct answer: a primary alcohol
  • A. Ethanoic acid
  • B. Propanoic acid
  • C. Trichloroethanoic acid
  • D. Butanoic acid

Explanation: Three electronegative chlorine atoms withdraw electron density powerfully and stabilise the carboxylate ion, so trichloroethanoic acid is…

Correct answer: Trichloroethanoic acid
  • A. fails to react with alkalis
  • B. acts as a reducing agent, giving a silver mirror with Tollens reagent
  • C. contains no carboxyl group
  • D. is insoluble in water

Explanation: Its carboxyl carbon also carries a hydrogen, so the molecule contains an aldehyde group as well and can be oxidised further to carbon…

Correct answer: acts as a reducing agent, giving a silver mirror with Tollens reagent
Very hard
  • A. they ionise completely
  • B. they are non polar
  • C. the carboxyl group forms hydrogen bonds with water molecules
  • D. they react with water chemically

Explanation: Both the carbonyl oxygen and the hydroxyl hydrogen can take part in hydrogen bonding with water, so the smaller acids dissolve freely, and…

Correct answer: the carboxyl group forms hydrogen bonds with water molecules
  • A. Sodium hydroxide solution
  • B. Sodium metal
  • C. Sodium hydrogen carbonate solution
  • D. Litmus paper alone

Explanation: Ethanoic acid gives brisk effervescence of carbon dioxide with hydrogen carbonate while phenol, being too weak an acid, gives no reaction…

Correct answer: Sodium hydrogen carbonate solution
  • A. Propionic acid
  • B. Cinnamic acid
  • C. Pyruvic acid
  • D. Tartaric acid

Explanation: Lactic acid, CH3CH(OH)COOH, contains a secondary alcohol group that alkaline potassium permanganate oxidizes to a ketone, giving…

Correct answer: Pyruvic acid
  • A. Depression of freezing point
  • B. Volumetric method
  • C. Victor Meyer's method
  • D. Osmosis method

Explanation: For a monobasic organic acid, volumetric analysis gives the amount of base required for neutralisation and can be used to calculate the…

Correct answer: Volumetric method
  • A. 3-Hydroxy propanoic acid
  • B. 2-Hydroxy propanoic acid
  • C. 2-hydroxy butanoic acid
  • D. 3-hydroxy butanoic acid

Explanation: Lactic acid has the structure CH3-CH(OH)-COOH, so its systematic name is 2-hydroxypropanoic acid.

Correct answer: 2-Hydroxy propanoic acid
  • A. alkane
  • B. alcohols
  • C. aldehydes
  • D. ketones

Explanation: HI with phosphorus is a strong reducing system that removes the carboxyl group of a carboxylic acid and converts the remaining carbon…

Correct answer: alkane
  • A. formic acid
  • B. acetic acid
  • C. propionic acid
  • D. butyric acid

Explanation: Butyric acid, CH3CH2CH2COOH, has a strong rancid or unpleasant smell and is associated with the odour of rancid butter.

Correct answer: butyric acid
  • A. C15H31COOH
  • B. C13H27COOH
  • C. C17H33COOH
  • D. C17H35COOH

Explanation: Palmitic acid is a saturated C16 fatty acid, so its formula is C15H31COOH, which contains 16 carbon atoms in total.

Correct answer: C15H31COOH
  • A. Citric acid
  • B. Benzoic acid
  • C. Tartaric acid
  • D. Oxalic acid

Explanation: Lemon juice contains a high concentration of citric acid, C6H8O7, which gives it its characteristic sour taste.

Correct answer: Citric acid
  • A. Water
  • B. Formic acid
  • C. Acetic acid
  • D. Propanoic acid

Explanation: Formic acid is the strongest of these weak acids because the alkyl groups in acetic and propanoic acids donate electron density toward the…

Correct answer: Formic acid
  • A. Lactic acid
  • B. Formic acid
  • C. Uric acid
  • D. Acetic acid

Explanation: Red ants inject formic acid, HCOOH, into the skin, and its acidic action causes the burning irritation.

Correct answer: Formic acid
  • A. malonic acid
  • B. oxalic acid
  • C. succinic acid
  • D. maleic acid

Explanation: Maleic acid is but-2-enedioic acid, containing a carbon-carbon double bond, so it is an unsaturated dicarboxylic acid.

Correct answer: maleic acid
  • A. Alkyne
  • B. Alkene
  • C. Alkane
  • D. Alcohol

Explanation: Complete reduction of a carboxylic acid removes the oxygen functionality and gives the corresponding alkane, for example RCOOH -> RCH3…

Correct answer: Alkane

Reactivity of Carboxylic Acids MCQs: common questions

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