Free Chemical Bonding MCQs with Answers

964 Chemical Bonding MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Chemical bonding explains molecular shape through VSEPR theory and distinguishes sigma bonds from pi bonds. Questions involve hybridization, bond angles, dipole moment and bond energy, including how electron-pair repulsion determines geometry and how bond polarity differs from the overall polarity of a molecule.

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964 questions · page 4 of 49

  • A. Sp2
  • B. Sp3
  • C. Sp
  • D. dsp2

Explanation: In BeCl2, beryllium forms two sigma bonds and has no lone pair on the central atom, giving two electron domains.

Correct answer: Sp
  • A. 115.5°
  • B. 109.5°
  • C. 105. 7°
  • D. 180°

Explanation: In methane, each carbon atom is sp3 hybridised and the four bonding orbitals point towards the corners of a tetrahedron.

Correct answer: 109.5°
  • A. All p-orbitals are involved
  • B. One s and 3 p-orbitals are involved
  • C. one p-orbital is involved
  • D. four p-orbitals are involved

Explanation: In sp3 hybridization, one s orbital mixes with three p orbitals of the same shell to form four equivalent sp3 hybrid orbitals.

Correct answer: One s and 3 p-orbitals are involved
  • A. Triangular
  • B. Tetrahedral
  • C. Square planner
  • D. Linear

Explanation: sp3 hybridization produces four equivalent hybrid orbitals directed toward the corners of a tetrahedron, giving tetrahedral geometry in a…

Correct answer: Tetrahedral
  • A. 2n
  • B. n
  • C. 3n
  • D. impossible to predict

Explanation: When n atomic orbitals mix, they produce n hybrid orbitals because orbital mixing conserves the total number of orbitals.

Correct answer: n
  • A. sp3
  • B. sp2
  • C. sp
  • D. All

Explanation: In O2, each oxygen is commonly described as sp2 hybridized: two sp2 orbitals form sigma bonds or hold lone pairs, while an unhybridized p…

Correct answer: sp2
  • A. sp2
  • B. sp
  • C. sp3
  • D. none of the above

Explanation: In a cyano group, the carbon is bonded through a triple bond, which requires one sigma bond and two pi bonds.

Correct answer: sp
  • A. square planar
  • B. trigonal pyramidal
  • C. tetrahedral
  • D. linear

Explanation: sp3 hybridization produces four equivalent hybrid orbitals directed toward the corners of a tetrahedron, giving a tetrahedral…

Correct answer: tetrahedral
  • A. 5 sigma bonds
  • B. 4 sigma and 1 pi bonds
  • C. 3 sigma and 2 pi bonds
  • D. 2 sigma and 3 pi bonds

Explanation: Acetylene has the structure H-C≡C-H. Each C-H bond is one sigma bond, and the carbon-carbon triple bond contains one sigma bond plus two…

Correct answer: 3 sigma and 2 pi bonds
  • A. Single covalent bond
  • B. Hydrogen bond
  • C. Double covalent bond
  • D. Coordinate covalent bond

Explanation: A coordinate covalent bond forms when one species donates both electrons of the shared electron pair, although the pair is then shared by…

Correct answer: Coordinate covalent bond
  • A. 2
  • B. 1
  • C. 3
  • D. 4

Explanation: In N2, the three shared electron pairs consist of one sigma bond and two pi bonds, so the bond order is 3.

Correct answer: 3
  • A. Bonding molecular orbital
  • B. Antibonding molecular orbital
  • C. Hybrid orbital
  • D. Super atomic orbital

Explanation: An antibonding molecular orbital results from destructive overlap and lies at higher energy than the combining atomic orbitals.

Correct answer: Antibonding molecular orbital
  • A. Un-hybrid orbitals
  • B. Hybrid orbitals
  • C. Hybrid and un hybrid orbitals
  • D. atomic orbital and hybrid orbital

Explanation: A pi bond forms by sideways overlap of parallel, unhybridized atomic orbitals, usually p orbitals, above and below the internuclear axis.

Correct answer: Un-hybrid orbitals
  • A. Bond
  • B. Attractive force
  • C. Interaction
  • D. All of above represent same entity

Explanation: The attractive force that holds atoms together in a compound through electron sharing or transfer is called a chemical bond.

Correct answer: Bond
  • A. Pi
  • B. Sigma
  • C. Both
  • D. Neither

Explanation: Two p orbitals can overlap end-to-end along the internuclear axis to form a sigma bond, or side-by-side to form a pi bond.

Correct answer: Both
  • A. propene
  • B. butanoic acid
  • C. butanal
  • D. ethoxy ethane

Explanation: Ethoxy ethane, CH3CH2-O-CH2CH3, contains only single bonds, and every single bond is a sigma bond.

Correct answer: ethoxy ethane
  • A. Two sigma bonds
  • B. Two Pi bonds
  • C. One sigma and one Pi bonds
  • D. One sigma and two Pi bonds

Explanation: A double bond consists of one sigma bond formed by head-on orbital overlap and one pi bond formed by sideways overlap of p orbitals.

Correct answer: One sigma and one Pi bonds
  • A. Trigonal bipyramidal
  • B. Linear
  • C. Square bipyramidal
  • D. Both A and C

Explanation: The triiodide ion, I3-, has five electron domains around the central iodine: two bonding pairs and three lone pairs.

Correct answer: Linear
  • A. O
  • B. 1
  • C. 2
  • D. 3

Explanation: In XeOF4, xenon has five bonding regions around it, consisting of four Xe-F bonds and one Xe=O region, plus one lone pair.

Correct answer: 1
  • A. Triangular
  • B. Square planner
  • C. Trigonal bipyramidal
  • D. Octahedral

Explanation: Five bonding electron pairs around a central atom arrange themselves as far apart as possible in a trigonal bipyramidal electron geometry…

Correct answer: Trigonal bipyramidal