Free Chemical Bonding MCQs with Answers

964 Chemical Bonding MCQs from Chemistry, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

Chemical bonding explains molecular shape through VSEPR theory and distinguishes sigma bonds from pi bonds. Questions involve hybridization, bond angles, dipole moment and bond energy, including how electron-pair repulsion determines geometry and how bond polarity differs from the overall polarity of a molecule.

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964 questions · page 23 of 49

  • A. N
  • B. CI
  • C. O
  • D. He

Explanation: He belongs to group 8A and has a stable electronic configuration.Electron affinity is inversely proportional to the stability of…

Correct answer: He
  • A. Ionization energy of A is high and electron affinity of B is low
  • B. Ionization energy of A is low and electron affinity of B is high
  • C. Both the ionization energy and the electron affinity of A and B are high
  • D. Both the ionization energy and the electron affinity of A and B are low

Explanation: Ionic compound is formed between the two atoms when one of them has low ionization energy so it can easily give away electrons and other…

Correct answer: Ionization energy of A is low and electron affinity of B is high
  • A. NaCI
  • B. CsF
  • C. KCI
  • D. HF

Explanation: Strength of ionic character depends upon electronegativity difference. CsF has greatest electronegativity difference of 3.19 and maximum…

Correct answer: CsF
  • A. OH-
  • B. BF-4
  • C. NH+4
  • D. H3O+

Explanation: OH-(hydroxide ion) does not have a dative bond. It is an example of a negatively charged ion formed through ionic bonding.

Correct answer: OH-
  • A. Nitride ion
  • B. Chloronium ion
  • C. Hydronium ion
  • D. All of these

Explanation: Yes, the hydronium ion (H3O+) contains a dative bond. The hydronium ion is formed when a water molecule (H2O) donates a lone pair of…

Correct answer: Hydronium ion
  • A. Ionic
  • B. Polar covalent
  • C. Non-polar covalent
  • D. Metallic

Explanation: The bond between two atoms is non-polar covalent if electronegativity difference between them is zero or less than 0.5.The bond between…

Correct answer: Polar covalent
  • A. CS2
  • B. CO2
  • C. SO2
  • D. BeCl2

Explanation: SO2 is a bent or V-shaped molecule. It has a bond angle of approximately 120 degrees between the sulfur atom (S) and the two oxygen atoms…

Correct answer: SO2
  • A. CH4
  • B. PCI5
  • C. NH+4
  • D. PCI3

Explanation: PCl3 has 3 single bonds with Cl and one lone pair.

Correct answer: PCI3
  • A. NH3, PH3
  • B. BF3, AIH3
  • C. H2O, C2H2
  • D. CO2, SO2

Explanation: BF3 and AIH3 are trigonal planar because each has three bond pairs only (AB3 type).

Correct answer: BF3, AIH3
  • A. Linear
  • B. Angular
  • C. Pyramidal
  • D. Tetrahedral

Explanation: NH2- ion has a total of 8 valence electrons. 2 pairs are bonding and 2 are non-bonding and stay confined to the Nitrogen atom.

Correct answer: Angular
  • A. Trigonal planar
  • B. Tetrahedral
  • C. Trigonal pyramidal
  • D. Angular

Explanation: Trigonal planar shape is only possible for AB3 type molecules.

Correct answer: Trigonal planar
  • A. CH4 >H2O> NF3 > H2S
  • B. H2S>H2O> CH4 > NF3
  • C. CH4 > NF3>H2O>H2S
  • D. CH4 >H2S> H2O > NF3

Explanation: CH4 (109.5°) > H2O (104.5°)> NF3 (102°) > H2S (92°)

Correct answer: CH4 >H2O> NF3 > H2S
  • A. CO2
  • B. PH3
  • C. NO
  • D. SO3

Explanation: SO3 is AB3 type with three bond pairs and no lone pair so it has perfect triangular structure.

Correct answer: SO3
  • A. It doesn't address the shapes of the molecules
  • B. It doesn't involve the criteria of bond formation
  • C. It doesn't explain paramagnetic behavior of O2
  • D. None of the above

Explanation: Paramagnetic behaviour of oxygen is explained by MOT not VBT.

Correct answer: It doesn't explain paramagnetic behavior of O2
  • A. Sigma bond
  • B. Pi bond
  • C. Metallic bond
  • D. Co-ordinate covalent bond

Explanation: End to end overlapping of orbitals is axial overlapping and is linear which results in sigma bond.

Correct answer: Sigma bond
  • A. Non-hybrid orbitals
  • B. Hybrid orbitals
  • C. Hybrid and non-hybrid orbitals
  • D. Atomic orbital and hybrid orbital

Explanation: π-bonds are formed by parallel overlapping of un-hybrid orbitals.

Correct answer: Non-hybrid orbitals
  • A. It does not explain paramagnetism of O2
  • B. It does not explain odd electron system
  • C. It could not explain tetravalency of carbon
  • D. All of above

Explanation: VBT does not explain tetravalency of carbon atom but concept of hybridization does.

Correct answer: It could not explain tetravalency of carbon
  • A. s-s orbital
  • B. p-p head on overlapping of orbitals
  • C. s-p orbital
  • D. p-p parallel overlapping of orbitals

Explanation: The Cl2 molecule is formed by the overlap of two chlorine atoms' atomic orbitals.

Correct answer: p-p head on overlapping of orbitals
  • A. Dissolution
  • B. Resonance
  • C. Hybridization
  • D. Ionization

Explanation: The process in which the orbitals of different energies and shape mix with each other to give equivalent hybrid orbitals is called…

Correct answer: Hybridization
  • A. NH+4
  • B. NH2-
  • C. NH3
  • D. NO3-

Explanation: In NO3- (Nitrate ion), the central nitrogen atom is in a hybridization state of sp2.

Correct answer: NO3-