All Free Chemistry MCQs with Answers

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13,720 questions · page 520 of 686

  • A. ∆H is always less than ∆E .
  • B. ∆H is always greater than ∆E .
  • C. ∆H is less than ∆E if the number of moles of gaseous products is greater than the number of moles of gaseous reactants.
  • D. ∆H is less than ∆E if the number of moles of gaseous products is less than the number of moles of gaseous reactants.

Explanation: As ∆H =∆E + ∆n0RT ∆H value is less than or greater than ∆E depending on the value of ∆ngwhich is the change in number of moles of the…

Correct answer: ∆H is less than ∆E if the number of moles of gaseous products is less than the number of moles of gaseous reactants.
  • A. Work
  • B. Enthalpy
  • C. Internal energy
  • D. Entropy

Explanation: The entropy concept is direct outcome of the second law of thermodynamics through the Carnot cycle approach.

Correct answer: Entropy
  • A. PΔV
  • B. -PΔV
  • C. PV
  • D. ΔPV

Explanation: Work done by the system is considered negative. (W=-PΔV)

Correct answer: -PΔV
  • A. Enthalpy
  • B. Work
  • C. Internal energy
  • D. Kinetic energy

Explanation: Enthalpy is a thermodynamic property of a system, denoted by the symbol H.

Correct answer: Enthalpy
  • A. Positive
  • B. Negative
  • C. Either positive or negative
  • D. None of the above

Explanation: Enthalpy of formation may be negative or positive. Mg(s) +1/2O2 → MgO(s) ΔHº f = -692kj / mol 1/2 N2(g) O2(g) → No2(g) ΔHº f = 33.18kj / mol

Correct answer: Either positive or negative
  • A. Heat content
  • B. Rate of reaction
  • C. Internal energy
  • D. Activation energy

Explanation: Total heat content of the system is called enthalpy. Enthalpy is a thermodynamic property of a system, denoted by the symbol H.

Correct answer: Heat content
  • A. Fe(g)
  • B. C(l)
  • C. Cu(s)
  • D. Na(g)

Explanation: Standard enthalpy of an element in its standard state is zero. Copper is a solid in standard form.

Correct answer: Cu(s)
  • A. Its value gives an idea about the relative stability of reactants and the products
  • B. It is always negative
  • C. Value depends upon nature of bonds
  • D. Its value may be negative or positive

Explanation: The standard enthalpy of formation of a compound is the amount of heat absorbed or evolved when one mole of compound is formed from its…

Correct answer: It is always negative
  • A. Neutralization
  • B. Combustion
  • C. Atomization
  • D. All of the above

Explanation: Enthalpy of neutralization & enthalpy of combustion are always negative while enthalpy of atomization is always positive.

Correct answer: Atomization
  • A. Enthalpy of reaction
  • B. Enthalpy of formation
  • C. Enthalpy of neutralization
  • D. Enthalpy of combustion

Explanation: The standard enthalpy of neutralization is the amount of heat evolved when one mole of H+ ions from an acid react with one mole of OH-…

Correct answer: Enthalpy of neutralization
  • A. 0°C and 1 atm pressure
  • B. 0 K and 1 atm pressure
  • C. 25°C and 1 atm pressure
  • D. 25°C and 2 atm pressure

Explanation: Standard conditions for enthalpy measurement are given below:Temperature =25°C (298 K), Pressure= 1 atm (760 torr).

Correct answer: 25°C and 1 atm pressure
  • A. 50 kJ
  • B. 100 kJ
  • C. 150 kJ
  • D. 5000 kJ

Explanation: It's calculated by subtracting the work done on the surroundings from the heat absorbed by the system.

Correct answer: 50 kJ
  • A. 84,000 J
  • B. -2000/4.2 J
  • C. 2000/4.2 J
  • D. -8400 J

Explanation: q=mxsxΔT =100x4.2x20=8400=-8400 JIt accurately represents the heat evolved when the temperature of the water decreases.

Correct answer: -8400 J
  • A. ΔΗlatt = ΔΗf- ΔΗx
  • B. ΔΗlatt = ΔΗf + ΔΗx
  • C. ΔΗlatt = ΔΗa + ΔΗv
  • D. ΔΗlatt = ΔΗf - ΔΗsol

Explanation: Option A is correct.The correct relationship to determine the lattice energy of an ionic compound is:ΔHlatt =ΔHf − ΔHx ΔHf is the heat of…

Correct answer: ΔΗlatt = ΔΗf- ΔΗx
  • A. Na(s) + 1/2 Cl2(g) → NaCl(s)
  • B. Na˕(aq) + Cl-(aq) → NaCl(aq)
  • C. Na(s) + Cl(g) → NaCl(s)
  • D. Na˕(g) + Cl-(g) → NaCl(s)

Explanation: Option D is correct.The equation that shows lattice energy for an ionic compound is: Na ˕ (g) + Cl ⁻ (g) → NaCl(s) This equation shows the…

Correct answer: Na˕(g) + Cl-(g) → NaCl(s)
  • A. ∆H°latt for ionic compound
  • B. ∆H° f for CO(g)
  • C. ∆H°f for B2O3
  • D. All of these

Explanation: The enthalpy of formation of an ionic compound cannot be measured directly.

Correct answer: All of these
  • A. +1258 kJ mol-1
  • B. +180 kJ mol-1
  • C. -184 kJ mol-1
  • D. -680 kJ mol-1

Explanation: Option C is correct.The standard enthalpy change of formation of propyne, CH3CCH is -184 kJ/mol.

Correct answer: -184 kJ mol-1
  • A. -3.37 kcal
  • B. +3.37 kcal
  • C. -33.7 kcal
  • D. 33.7 kcal

Explanation: Option C is correct.The heat of combustion of ethane (C2H6) is -337.0 kcal at 25°C.

Correct answer: -33.7 kcal
  • A. Spontaneous
  • B. Decomposition
  • C. Non-spontaneous
  • D. Hydrolysis

Explanation: Option a is correct because the evaporation of water is a process that occurs naturally without requiring an external input of energy.

Correct answer: Spontaneous
  • A. Atomization
  • B. Combustion
  • C. Neutralization
  • D. Solution

Explanation: A is correct. Atomization involves bond breaking and bond breaking is endothermic.

Correct answer: Atomization