Free Chemical Reaction Engineering MCQs with Answers

395 Chemical Reaction Engineering MCQs from Chemical Engineering, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.

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395 questions · page 10 of 20

  • A. Semi-batch
  • B. Tubular
  • C. Batch
  • D. Back-mix

Explanation: A back-mix reactor, or ideal CSTR, is perfectly mixed, so the composition is uniform throughout the vessel and equals the outlet…

Correct answer: Back-mix
  • A. Activation energy
  • B. Equilibrium constant
  • C. Heat of reaction
  • D. None of these

Explanation: A catalyst provides an alternative reaction pathway with a lower activation energy, increasing the forward and reverse rates.

Correct answer: Activation energy
  • A. Consecutive
  • B. Parallel
  • C. Elementary
  • D. None of these

Explanation: Chlorination occurs through successive substitutions: benzene forms chlorobenzene, then dichlorobenzene, and finally trichlorobenzene.

Correct answer: Consecutive
  • A. N2 + O2 ⇌ 2NO
  • B. PCl3 + Cl2 ⇌ PCl5
  • C. N + 3H2 ⇌ 2NH3
  • D. 2SO2 + O2 ⇌ 2SO3

Explanation: For N₂ + O₂ ⇌ 2NO, the total number of gas moles is unchanged, so pressure does not shift the equilibrium yield.

Correct answer: N2 + O2 ⇌ 2NO
  • A. Continuously increases
  • B. Continuously decreases
  • C. Passes through a minimum
  • D. Passes through a maximum

Explanation: At first, the exothermic reaction accelerates because the adiabatic temperature rises, but as conversion increases the reversible reaction…

Correct answer: Passes through a maximum
  • A. Very temperature sensitive
  • B. Temperature insensitive
  • C. Always irreversible
  • D. Always reversible

Explanation: From the Arrhenius equation, a high activation energy makes the rate constant change sharply with temperature.

Correct answer: Very temperature sensitive
  • A. (FA0/V) - (dCA/dt)
  • B. (FA0/V) XA
  • C. (FA0/V) + (dCA/dt)
  • D. -(dCA/dt)

Explanation: For a steady-state mixed reactor, the exit concentration equals the reactor concentration, and the material balance gives -rA = FA0XA/V.

Correct answer: (FA0/V) XA
  • A. Remain same
  • B. Decreases
  • C. Increases
  • D. Increases linearly

Explanation: For a positive-order reaction, a mixed reactor evaluates the rate at the lowest concentration, the exit concentration, while a plug-flow…

Correct answer: Increases
  • A. Zero order & K1/K2
  • B. Zero order & K1
  • C. First order & K1
  • D. First order & K1/K2

Explanation: When K2Cx is much greater than one, the denominator is approximately K2Cx, so -rx becomes (K1/K2), independent of concentration.

Correct answer: Zero order & K1/K2
  • A. ∞
  • B. 0
  • C. 1
  • D. -1

Explanation: The dispersion number measures axial mixing relative to plug flow. Ideal plug flow has no axial dispersion, so its dispersion number is…

Correct answer: 0
  • A. K α e-E/RT
  • B. K α eE/RT
  • C. K α T . e-E/RT
  • D. K α √T . e-E/RT

Explanation: Transition state theory includes a frequency term proportional to temperature, giving k proportional to T exp(-E/RT) in the simplified…

Correct answer: K α T . e-E/RT
  • A. exp (-E/RT)
  • B. exp (-E/2RT)
  • C. √T
  • D. Tm exp (-E/RT)

Explanation: Collision theory combines the collision-frequency factor, commonly represented by T^m, with the fraction of collisions having enough…

Correct answer: Tm exp (-E/RT)
  • A. Same as that of rate constant
  • B. Same as that of activation energy
  • C. Dimensionless
  • D. None of these

Explanation: In k = A exp(-E/RT), the exponential is dimensionless, so A must carry the same units as k.

Correct answer: Same as that of rate constant
  • A. Operational yield
  • B. Selectivity
  • C. Relative yield
  • D. None of these

Explanation: Selectivity compares the amount of desired product, or reactant consumed to form it, with the corresponding amount forming unwanted…

Correct answer: Selectivity
  • A. For CSTR
  • B. For large diameter tubular reactor
  • C. For narrow diameter tubular reactor
  • D. When the density of the reaction mixture is constant

Explanation: Space time is based on reactor volume divided by inlet volumetric flow, whereas mean residence time uses the actual flow within the…

Correct answer: When the density of the reaction mixture is constant
  • A. All A., B. and C.
  • B. Temperature of the system
  • C. Pressure of the system
  • D. Composition of the component only

Explanation: Reaction rate is affected by composition through concentrations or partial pressures and by temperature through the rate constant…

Correct answer: All A., B. and C.
  • A. (1/k) ln C/C0
  • B. (1/k) ln C0/C
  • C. k ln C0/C
  • D. k ln C/C0

Explanation: For a first-order reaction in a constant-density plug flow reactor, integrating dC/dτ = -kC gives τ = (1/k) ln(C0/C).

Correct answer: (1/k) ln C0/C
  • A. 3 hours
  • B. The time required to process one reactor volume of feed (measured at specified conditions) is
  • C. Three reactor volumes of feed can be processed every hour
  • D. It takes three hours to dump the entire volume of the reactor with feed
  • E. Conversion is cent per cent after three hours

Explanation: Space time is the reactor volume divided by the volumetric feed rate, so it represents the time needed to process one reactor volume of…

Correct answer: The time required to process one reactor volume of feed (measured at specified conditions) is
  • A. t ∝ 1/an
  • B. t ∝ 1/an - 1
  • C. t ∝ 1/an + 1
  • D. t ∝ an

Explanation: For a fixed fractional conversion in an nth-order batch reaction, the time scales as the inverse of the initial concentration raised to…

Correct answer: t ∝ 1/an - 1