Free Chemical Reaction Engineering MCQs with Answers
395 Chemical Reaction Engineering MCQs from Chemical Engineering, each with the correct answer and a written explanation of why it is correct. Free and unlimited, with no account needed.
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- A. Semi-batch
- B. Tubular
- C. Batch
- D. Back-mix
Explanation: A back-mix reactor, or ideal CSTR, is perfectly mixed, so the composition is uniform throughout the vessel and equals the outlet…
Correct answer: Back-mix- A. Activation energy
- B. Equilibrium constant
- C. Heat of reaction
- D. None of these
Explanation: A catalyst provides an alternative reaction pathway with a lower activation energy, increasing the forward and reverse rates.
Correct answer: Activation energy- A. Consecutive
- B. Parallel
- C. Elementary
- D. None of these
Explanation: Chlorination occurs through successive substitutions: benzene forms chlorobenzene, then dichlorobenzene, and finally trichlorobenzene.
Correct answer: Consecutive- A. N2 + O2 ⇌ 2NO
- B. PCl3 + Cl2 ⇌ PCl5
- C. N + 3H2 ⇌ 2NH3
- D. 2SO2 + O2 ⇌ 2SO3
Explanation: For N₂ + O₂ ⇌ 2NO, the total number of gas moles is unchanged, so pressure does not shift the equilibrium yield.
Correct answer: N2 + O2 ⇌ 2NO- A. Continuously increases
- B. Continuously decreases
- C. Passes through a minimum
- D. Passes through a maximum
Explanation: At first, the exothermic reaction accelerates because the adiabatic temperature rises, but as conversion increases the reversible reaction…
Correct answer: Passes through a maximum- A. Very temperature sensitive
- B. Temperature insensitive
- C. Always irreversible
- D. Always reversible
Explanation: From the Arrhenius equation, a high activation energy makes the rate constant change sharply with temperature.
Correct answer: Very temperature sensitive187. For a mixed flow reactor operating at steady state, the rate of reaction is given by______________?
- A. (FA0/V) - (dCA/dt)
- B. (FA0/V) XA
- C. (FA0/V) + (dCA/dt)
- D. -(dCA/dt)
Explanation: For a steady-state mixed reactor, the exit concentration equals the reactor concentration, and the material balance gives -rA = FA0XA/V.
Correct answer: (FA0/V) XA- A. Remain same
- B. Decreases
- C. Increases
- D. Increases linearly
Explanation: For a positive-order reaction, a mixed reactor evaluates the rate at the lowest concentration, the exit concentration, while a plug-flow…
Correct answer: Increases- A. Zero order & K1/K2
- B. Zero order & K1
- C. First order & K1
- D. First order & K1/K2
Explanation: When K2Cx is much greater than one, the denominator is approximately K2Cx, so -rx becomes (K1/K2), independent of concentration.
Correct answer: Zero order & K1/K2- A. ∞
- B. 0
- C. 1
- D. -1
Explanation: The dispersion number measures axial mixing relative to plug flow. Ideal plug flow has no axial dispersion, so its dispersion number is…
Correct answer: 0- A. K α e-E/RT
- B. K α eE/RT
- C. K α T . e-E/RT
- D. K α √T . e-E/RT
Explanation: Transition state theory includes a frequency term proportional to temperature, giving k proportional to T exp(-E/RT) in the simplified…
Correct answer: K α T . e-E/RT- A. exp (-E/RT)
- B. exp (-E/2RT)
- C. √T
- D. Tm exp (-E/RT)
Explanation: Collision theory combines the collision-frequency factor, commonly represented by T^m, with the fraction of collisions having enough…
Correct answer: Tm exp (-E/RT)- A. Same as that of rate constant
- B. Same as that of activation energy
- C. Dimensionless
- D. None of these
Explanation: In k = A exp(-E/RT), the exponential is dimensionless, so A must carry the same units as k.
Correct answer: Same as that of rate constant- A. Operational yield
- B. Selectivity
- C. Relative yield
- D. None of these
Explanation: Selectivity compares the amount of desired product, or reactant consumed to form it, with the corresponding amount forming unwanted…
Correct answer: Selectivity- A. For CSTR
- B. For large diameter tubular reactor
- C. For narrow diameter tubular reactor
- D. When the density of the reaction mixture is constant
Explanation: Space time is based on reactor volume divided by inlet volumetric flow, whereas mean residence time uses the actual flow within the…
Correct answer: When the density of the reaction mixture is constant- A. All A., B. and C.
- B. Temperature of the system
- C. Pressure of the system
- D. Composition of the component only
Explanation: Reaction rate is affected by composition through concentrations or partial pressures and by temperature through the rate constant…
Correct answer: All A., B. and C.197. For a first order reaction carried out in a plug flow reactor, the space time is__________________?
- A. (1/k) ln C/C0
- B. (1/k) ln C0/C
- C. k ln C0/C
- D. k ln C/C0
Explanation: For a first-order reaction in a constant-density plug flow reactor, integrating dC/dτ = -kC gives τ = (1/k) ln(C0/C).
Correct answer: (1/k) ln C0/C- A. 3 hours
- B. The time required to process one reactor volume of feed (measured at specified conditions) is
- C. Three reactor volumes of feed can be processed every hour
- D. It takes three hours to dump the entire volume of the reactor with feed
- E. Conversion is cent per cent after three hours
Explanation: Space time is the reactor volume divided by the volumetric feed rate, so it represents the time needed to process one reactor volume of…
Correct answer: The time required to process one reactor volume of feed (measured at specified conditions) is- A. 2/3 kW
- B. 1 kW
- C. 5/3 kW
- D. 4 kW
Explanation: The heat released is qCA0XA|ΔH| = (10⁻³)(5)(0.5)(40,000) kJ/min = 100 kJ/min, or 1.67 kW.
Correct answer: 5/3 kW- A. t ∝ 1/an
- B. t ∝ 1/an - 1
- C. t ∝ 1/an + 1
- D. t ∝ an
Explanation: For a fixed fractional conversion in an nth-order batch reaction, the time scales as the inverse of the initial concentration raised to…
Correct answer: t ∝ 1/an - 1