Asked in UHS MDCAT 2017 2017Moderate

Which one of the following compounds will give iodoform test on treatment with aqueous iodine?

Correct answer: B. Propanone

  • A. 3-pentanone
  • B. Propanone
  • C. Propanal
  • D. Butanal

Explanation

Compounds that give a positive iodoform test are primary alcohol, methyl alcohol and methyl ketones. Propanone gives a positive iodoform test since C=O is bonded to CH3

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About Reactivity of Aldehydes and Ketones

The polar carbonyl group makes aldehydes and ketones undergo nucleophilic addition, reduction and condensation reactions. Aldehydes are generally more reactive and oxidise readily to carboxylic acids, whereas ketones resist mild oxidation; reactions with hydrogen cyanide, sodium bisulfite and 2,4-DNP help identify their behaviour.

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