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Which of the following species has lone pair of electrons on central atom?

Correct answer: D. PCl3

  • A. CH4
  • B. PCl5
  • C. NH4+
  • D. PCl3

Explanation

The correct answer is PCl3. In PCl3, the central phosphorus atom forms three single bonds with chlorine atoms and has one lone pair of electrons, resulting in a trigonal pyramidal shape. In contrast, CH4, PCl5, and NH4+ all have central atoms with no lone pairs of electrons, leading to geometries of tetrahedral and trigonal bipyramidal, respectively.

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Chemical bonding explains molecular shape through VSEPR theory and distinguishes sigma bonds from pi bonds. Questions involve hybridization, bond angles, dipole moment and bond energy, including how electron-pair repulsion determines geometry and how bond polarity differs from the overall polarity of a molecule.

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