Asked in PMC Practice Test 11 (2021) 2021

Which of the following major product(s) is formed when phenol reacts with sulphuric acid at 100 °C?

Correct answer: B. Para-hydroxy benzene sulphonic acid

  • A. Ortho-hydroxy benzene sulphonic acid
  • B. Para-hydroxy benzene sulphonic acid
  • C. Meta-hydroxybenzene sulphonic acid
  • D. Both a and b

Explanation

The reaction of phenol with concentrated sulphuric acid is thermodynamically controlled. at 25 Celsius the Ortho product predominates while at 100 Celsius the Para product is the major product.

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About Phenols

Phenols contain a hydroxyl group directly bonded to an aromatic ring, making them more acidic than alcohols because the phenoxide ion is resonance-stabilised. Reactions include ionisation with bases, electrophilic substitution, bromination, nitration and oxidation, with attention to the difference between phenols and aliphatic alcohols.

Practise Alcohols and Phenols

535 free Alcohols and Phenols MCQs from Chemistry, each with the correct answer and an explanation. Unlimited attempts, no account needed.

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