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Which of the following is best method to prepare alkyl halides from alcohols?

Correct answer: B. Reaction of alcohol with SOCl2

  • A. Reaction of alcohol with HX
  • B. Reaction of alcohol with SOCl2
  • C. Reaction of Alcohol with PCl3
  • D. Reaction of Alcohol with PCI5

Explanation

Option B is the best method to prepare alkyl halides from alcohols because it involves the reaction of alcohol with thionyl chloride (SOCl2). Thionyl chloride is commonly used to convert alcohols into alkyl chlorides. It is a relatively mild and selective reagent for this purpose.

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About Alkyl Halides

Alkyl halides are named and related to their carbon-halogen structure, polarity and reactivity. The key reactions are nucleophilic substitution by SN1 and SN2 mechanisms and elimination by E1 and E2 mechanisms, including how substrate structure, nucleophile, base, solvent and temperature influence substitution versus elimination.

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