Moderate

Which of the following does not act as ligand in the formation of complexes?

Correct answer: D. NH4+

  • A. CH3NH2
  • B. OH-
  • C. Cl-
  • D. NH4+

Explanation

Ligand is a species that donates a lone pair of electrons by forming a dative coordinate bond with a central metal atom/ion. NH4+ has no lone pair of electrons because 4 of the valence electrons of nitrogen are involved in forming covalent bonds with hydrogen and 1 electron has been lost by it, being an ion of +1 charge. Therefore it cannot form a dative bond and hence cannot act as a ligand. The correct answer is therefore option D.

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About Transition Elements

Transition elements are identified by their partially filled d subshells in atoms or common ions. The topic covers the electronic structure of d-block elements, including the filling order of 4s and 3d orbitals, variable oxidation states and the distinction between transition elements and elements with completely filled d subshells.

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