Moderate

When two moles of ethyl chloride react with two moles of sodium in the presence of ether what will be formed ?

Correct answer: D. 1 mole of butane

  • A. 2 moles of ethane
  • B. 1 mole of ethane
  • C. 2 moles of butane
  • D. 1 mole of butane

Explanation

The Wurtz reaction couples two ethyl groups: 2 C2H5Cl + 2 Na → C2H5-C2H5 + 2 NaCl. One molecule of butane is therefore produced from two moles of ethyl chloride, so the product amount is 1 mole of butane. Students may choose 2 moles of butane by assuming each mole of ethyl chloride independently gives a molecule of product.

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About Alkanes

Alkanes are saturated hydrocarbons containing only carbon-carbon and carbon-hydrogen single bonds, with the general formula CnH2n+2 for open chains. Their structure, isomerism, IUPAC nomenclature, physical properties, combustion, free-radical halogenation and conformations are covered, including the difference between substitution in alkanes and addition in unsaturated hydrocarbons.

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