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What is the reason for the reactivity of the Grignard reagent?

Correct answer: C. Polarity of C-Mg bond

  • A. Presence of Mg atom
  • B. Polarity of C-H bond
  • C. Polarity of C-Mg bond
  • D. Presence of electrophilic carbon

Explanation

Option A is incorrect because only the presence of the Mg atom doesn't make Grignard reagent reactive. Option B is wrong because the polarity of the C-H bond doesn't make Grignard reagent reactive. Option: C Grignard reagents are much more reactive than most of the organic compounds. The reactivity is due to the nature of the C-Mg bond which is highly polar. Magnesium is more electropositive than carbon and the C-Mg bond through covalent is highly polar, giving alkyl carbon a partial negative charge. The negative charge is of unusual character which makes the alkyl groups highly reactive towards the electrophile centre. Most reactions shown by Grignard reagents are exothermic. Option D : The presence of electrophilic carbon does not make a Grignard reagent reactive because Grignard reagents are themselves nucleophiles, and they prefer to attack electrophilic species rather than being attacked by them.

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About Alkyl Halides

Alkyl halides are named and related to their carbon-halogen structure, polarity and reactivity. The key reactions are nucleophilic substitution by SN1 and SN2 mechanisms and elimination by E1 and E2 mechanisms, including how substrate structure, nucleophile, base, solvent and temperature influence substitution versus elimination.

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