The reaction of formaldehyde with HCN is:
Correct answer: B. Nucleophilic addition
- A. Nucleophilic substitution
- B. Nucleophilic addition
- C. Electrophilic substitution
- D. Free radical addition
Explanation
The reaction of formaldehyde (HCHO) with hydrogen cyanide (HCN) involves a nucleophilic addition rather than a nucleophilic substitution.In a nucleophilic addition reaction, a nucleophile adds to a molecule, typically at a carbon-carbon double bond (as in alkenes and carbonyl compounds), resulting in the formation of a new compound.In the case of formaldehyde and HCN, the oxygen atom of formaldehyde's carbonyl group (C=O) acts as the electrophilic site, while the cyanide ion (CN⁻) acts as the nucleophile. The CN⁻ attacks the carbon atom of the carbonyl group, and the reaction results in the formation of a hydroxynitrile compound (a cyanohydrin). This addition reaction leads to the creation of a new carbon-carbon bond and the replacement of the oxygen atom with the cyanide group.Nucleophilic substitution reactions, on the other hand, involve the replacement of a leaving group in a molecule by a nucleophile. In the case of formaldehyde and HCN, no leaving group is being substituted by the cyanide ion, so it is not a nucleophilic substitution reaction.In summary, the reaction of formaldehyde with HCN is an example of nucleophilic addition.
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Aldehydes and ketones contain the polar carbonyl group, but aldehydes are generally more readily oxidised and more reactive than ketones. Coverage includes preparation by oxidation or reduction routes, nucleophilic addition of reagents such as hydrogen cyanide and bisulfite, and tests that distinguish aldehydes from ketones.
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