The potential set up when an electrode is in contact with 1M solution of its ions at 298 K is known as standard electrode potential (or standard reduction potential denoted by E°). All of the following statements about standard electrode potential are correct EXCEPT:

Correct answer: D. E°red of Cl2 is maximum (+2.87V)

  • A. The smaller the E°red, the greater the reducing power of a metal
  • B. E°rcd of Li1 is minimum (-3.04V)
  • C. The greater the E°red, the greater the oxidizing power of a non-metal
  • D. E°red of Cl2 is maximum (+2.87V)

Explanation

The statement that E°red of Cl2 is maximum (+2.87V) is incorrect. Chlorine has a high E°red because it is a strong oxidizing agent. However, the maximum E°red for any substance is +1.23V, which is the value for fluorine. Therefore, the E°red of Cl2 cannot be greater than +1.23V.

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