Asked in ETEA MDCAT 2005 2005Moderate

The net heat change in a chemical reaction is smae weather it takes place in one ste or several steps. This law is known as:

Correct answer: C. Hess's law

  • A. First law of thermodynamics
  • B. Henery's law
  • C. Hess's law
  • D. Joule's law

Explanation

Option A: The first law of thermodynamics states that energy can neither be created nor destroyed, only altered in form. Hence incorrect. Option B: Henry's law is a gas law that states that the amount of dissolved gas in a liquid is directly proportional to its partial pressure above the liquid. The proportionality factor is called Henry's law constant. Hence incorrect. Option C: Hess's law states that the overall change in enthalpy for a chemical reaction is equal to the sum of the enthalpy changes for each step. And this is independent of the path taken. Hence it is the correct option. Option D: Joule's law states that the amount of generated heat in a conductor carrying current is proportional to the square of the current flow through the circuit when the electrical resistance and current supply are constant. Hence incorrect.

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About Hess's Law

Hess's law states that the enthalpy change of a reaction is independent of the route because enthalpy is a state function. Calculations involve reversing and adding thermochemical equations, using standard enthalpies of formation or combustion, and finding an unknown reaction enthalpy without confusing enthalpy change with reaction rate.

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