Asked in HEC Phase I 2017 2017Moderate

The correct increasing order of electron affinity value of atom is:

Correct answer: A. I < Br < F < Cl

  • A. I < Br < F < Cl
  • B. I < Cl < F < Br
  • C. I < F < Br < Cl
  • D. F < Cl < Br < I

Explanation

Option A is correct as Cl has the highest E.A in its group. Although Fluorine is expected to have the highest E.A but due to its small size and large electron density there are electron-electron repulsions and hence some energy is used in overcoming those repulsions. Thus the order of E.A becomes; I<Br<F<Cl. All other options are incorrect.

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About Periodic Properties and Trends

Periodic properties arise from electron configuration and effective nuclear charge, producing trends in atomic and ionic radius, ionization energy, electron affinity, electronegativity, metallic character and reactivity. Comparisons run across periods and down groups, with attention to common exceptions. The topic also relates these trends to the behavior of s-block and p-block elements.

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