Asked in UHS MDCAT 2009 2009Moderate

Solubility of KCIO; can be decreased in H2O by:

Correct answer: C. Adding KCl from outside

  • A. Removing K+ ions from the solution
  • B. Removing ClO3- ions from the solution
  • C. Adding KCl from outside
  • D. Adding NaNO3 from outside

Explanation

Explanation:Adding KCl would increase the K+ ion concentration thus shifting the equilibrium to the left due to common ion effect, thus decreasing solubility of KClO3.Removing K+ ions from the solution, would increase the solubility of KClO3, as there would be less competition for the water molecules by K+ ions. Removing ClO3-1 ions from the solution, would also increase the solubility of KClO3, as there would be fewer anions in the solution to repel the ClO3-1 ions. Adding NaNO3 from outside, would not have any effect on the solubility of KClO3, as it is a different compound and does not interact with KClO3 in water to affect its solubility.

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About Common Ion Effect

The common ion effect is the reduction in the ionisation of a weak electrolyte or the solubility of a sparingly soluble salt when a solution already contains one of its ions. Questions apply Le Chatelier's principle, equilibrium constants and solubility product expressions to predict the shift and calculate concentrations.

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